In manganese electrolysis,electrochemical oscillations and manganese dendrite growth are typical nonlinear phenomena critical for energy consumption reduction.Nonetheless,existing research lacks a deep understanding o...In manganese electrolysis,electrochemical oscillations and manganese dendrite growth are typical nonlinear phenomena critical for energy consumption reduction.Nonetheless,existing research lacks a deep understanding of their underlying mechanisms.In this study,we systematically explored the evolution of anode electrochemical oscillations during manganese electrolysis and designed a square wave circuit to effectively suppress oscillations and dendrite growth while reducing energy consumption.A novel four-dimensional differential equation was introduced to explore the internal dynamic mechanisms of typical nonlinear behaviors.The experimental results showed that while the evolutionary patterns of current and potential oscillation signals were consistent,their waveform directions were opposite.The square wave current effectively suppressed both electrochemical oscillations and the growth of manganese dendrites.Furthermore,compared to direct current electrolysis,the square wave current improved the current efficiency by 3.6%and reduced the energy consumption by 0.32 kW·h·kg^(−1).展开更多
Manganese oxide ores from Gabon and Xiangxi were leached with waste tea as reductant in dilute sulfuric acid solution. The effects of waste tea dosage, concentration of sulfuric acid, liquid-to-solid ratio, leaching t...Manganese oxide ores from Gabon and Xiangxi were leached with waste tea as reductant in dilute sulfuric acid solution. The effects of waste tea dosage, concentration of sulfuric acid, liquid-to-solid ratio, leaching temperature and reaction time on leaching process were explored. The leaching efficiency of Gabonese manganese oxide ore reached almost 100% under the optimal condition which was determined as follows： manganese oxide ore to waste tea mass ratio of 10：1, sulfuric acid concentration of 2.5 molFL, liquid-to-solid ratio of 7.5：1, leaching temperature of 368 K, time of 8 h. The leaching efficiency of Xiangxi manganese oxide ore reached 99.8% under the optimal condition which was determined as follows： manganese oxide ore to waste tea mass ratio of 10：1, sulfuric acid concentration of 1.7 mol/L, liquid-to-solid ratio of 7.5：1, leaching temperature of 368 K, time of 8 h. The leaching process followed the internal diffusion controlled kinetic model, and the apparent activation energies of Gabonese manganese oxide ore and Xiangxi manganese oxide ore were calculated to be 38.2 kJ/mol and 20.4 kJ/mol, respectively. The morphological changes and mineralogical forms of the ore before and after the chemical treatment were discussed with the support of XRD analysis and SEM analysis.展开更多
基金support from the Fundamental Research Funds for the Central Universities(2022CDJQY-005,2024CDJXY010)the Guangxi Science and Technology Program(AB24010229)is greatly acknowledged.
文摘In manganese electrolysis,electrochemical oscillations and manganese dendrite growth are typical nonlinear phenomena critical for energy consumption reduction.Nonetheless,existing research lacks a deep understanding of their underlying mechanisms.In this study,we systematically explored the evolution of anode electrochemical oscillations during manganese electrolysis and designed a square wave circuit to effectively suppress oscillations and dendrite growth while reducing energy consumption.A novel four-dimensional differential equation was introduced to explore the internal dynamic mechanisms of typical nonlinear behaviors.The experimental results showed that while the evolutionary patterns of current and potential oscillation signals were consistent,their waveform directions were opposite.The square wave current effectively suppressed both electrochemical oscillations and the growth of manganese dendrites.Furthermore,compared to direct current electrolysis,the square wave current improved the current efficiency by 3.6%and reduced the energy consumption by 0.32 kW·h·kg^(−1).
基金Project(2010FJ1011)supported by the Major Project of Hunan Science and Technology,ChinaProject(cstc2012ggB90002)supported by the Chongqing Key Science and Technology Program,China
文摘Manganese oxide ores from Gabon and Xiangxi were leached with waste tea as reductant in dilute sulfuric acid solution. The effects of waste tea dosage, concentration of sulfuric acid, liquid-to-solid ratio, leaching temperature and reaction time on leaching process were explored. The leaching efficiency of Gabonese manganese oxide ore reached almost 100% under the optimal condition which was determined as follows： manganese oxide ore to waste tea mass ratio of 10：1, sulfuric acid concentration of 2.5 molFL, liquid-to-solid ratio of 7.5：1, leaching temperature of 368 K, time of 8 h. The leaching efficiency of Xiangxi manganese oxide ore reached 99.8% under the optimal condition which was determined as follows： manganese oxide ore to waste tea mass ratio of 10：1, sulfuric acid concentration of 1.7 mol/L, liquid-to-solid ratio of 7.5：1, leaching temperature of 368 K, time of 8 h. The leaching process followed the internal diffusion controlled kinetic model, and the apparent activation energies of Gabonese manganese oxide ore and Xiangxi manganese oxide ore were calculated to be 38.2 kJ/mol and 20.4 kJ/mol, respectively. The morphological changes and mineralogical forms of the ore before and after the chemical treatment were discussed with the support of XRD analysis and SEM analysis.
