The photovoltaic features and photo-induced interfacial charge transfer of CuPc-modified Q-CdS films were investigated by surface photovoltage spectra and optical absorption spectra. The results show that the interfac...The photovoltaic features and photo-induced interfacial charge transfer of CuPc-modified Q-CdS films were investigated by surface photovoltage spectra and optical absorption spectra. The results show that the interfacial chaxge transfer and photosensitization between cuPc and Q-cds occur under inuAnnation. Based on the observations,the generation and processes of the charge transfer are proposed and discussed.展开更多
Nickel-palladium film on p-Si prepared by potential -controlled electrodeposition has much better adherence than that deposited by other methods .To reveal the reasons of this effect ,X-ray photoelectron spectroscopy ...Nickel-palladium film on p-Si prepared by potential -controlled electrodeposition has much better adherence than that deposited by other methods .To reveal the reasons of this effect ,X-ray photoelectron spectroscopy (XPS) combmed with Ar+sput tering was used to investigate the interface of NiPd /Si .The results showed that dramatic interdiffusion of Ni, Pd and Si had occurred at atmospheric temperature .On the XPS spectra of mckel and palladium ,there are two kinds of binding energy ,contributed by pure metals and metal silicide respectively. NiSi, PdSi and Pd2Si were formed at the interface. Both of the electric field on the surface and the H atoms in the metal lattice have the possibility to promote reactions between nickel or palladium and silicon .展开更多
文摘The photovoltaic features and photo-induced interfacial charge transfer of CuPc-modified Q-CdS films were investigated by surface photovoltage spectra and optical absorption spectra. The results show that the interfacial chaxge transfer and photosensitization between cuPc and Q-cds occur under inuAnnation. Based on the observations,the generation and processes of the charge transfer are proposed and discussed.
基金安徽省高等学校省级质量工程项目“基于工程教育认证的专业基础课教学革研究——以无机化学课程为例”(2022jyxm1309)安徽省高等学校省级质量工程项目“新工科背景下科学史情境的建构教学在材料化工类专业《物理化学》课程中的探索与实践”(2023jyxm0574)安徽省高校科学研究重点项目“0D/1D TiO 2基S型异质结复合物的构建及其光催化性能研究”(2023AH051326)。
文摘Nickel-palladium film on p-Si prepared by potential -controlled electrodeposition has much better adherence than that deposited by other methods .To reveal the reasons of this effect ,X-ray photoelectron spectroscopy (XPS) combmed with Ar+sput tering was used to investigate the interface of NiPd /Si .The results showed that dramatic interdiffusion of Ni, Pd and Si had occurred at atmospheric temperature .On the XPS spectra of mckel and palladium ,there are two kinds of binding energy ,contributed by pure metals and metal silicide respectively. NiSi, PdSi and Pd2Si were formed at the interface. Both of the electric field on the surface and the H atoms in the metal lattice have the possibility to promote reactions between nickel or palladium and silicon .
