The Michael addition reactions of Z and E 4-methyl-benzaldoximes with propene were investigated theoretically by DFT method at B3LYP/6-31G* level.The calculation results show that both addition reactions are concerted...The Michael addition reactions of Z and E 4-methyl-benzaldoximes with propene were investigated theoretically by DFT method at B3LYP/6-31G* level.The calculation results show that both addition reactions are concerted processes accompanied by the migration of hydrogen from the atom oxygen to carbon.Both products Z and E nitrones have dipolar charge distributions and activities.Z isomer is more favorable in the reaction due to the barrier is lower.展开更多
In-situ Al2O3/TiAl composites were successfully synthesized from the starting powders of Ti, Al, TiO2 and Nb2O5. The oxidation behavior of the composites at 900℃ in static air was investigated. The results indicate t...In-situ Al2O3/TiAl composites were successfully synthesized from the starting powders of Ti, Al, TiO2 and Nb2O5. The oxidation behavior of the composites at 900℃ in static air was investigated. The results indicate that the composite samples present a much lower oxidation mass gain. Under long-time intensive oxidation exposure, the formed oxide scale is multi-layer. The formation of the outer TiO2 layer is fine and dense, the internal Al2O3 scale has good adhesiveness with the outer TiO2 scale, and the TiO2＋Al2O3 mixed layer forming the protective oxide scale is favorable for the improvement of oxidation resistance. It is believed that the incorporation of Al2O3 particulates into the metal matrix decreases the coefficient of thermal expansion of the substrate, and forms a local three-dimensional network structure that can hold the oxide scale. The formation of the oxide scale with finer particle size, stronger adherence, less micro-defects and slower growth rate can contribute to the improvement of oxidation resistance. Nb element plays an important role in reducing the internal oxidation action of the materials, restraining the growth of TiO2 crystals and promoting the stable formation of the Al2O3-riched layer, which is beneficial to improve the oxidation properties.展开更多
This work is aimed at showing that the ＂band structure＂ of the energy distribution in solids which is a well-known model for electronic engineers and solid-state physics scientists is an efficacious description also...This work is aimed at showing that the ＂band structure＂ of the energy distribution in solids which is a well-known model for electronic engineers and solid-state physics scientists is an efficacious description also for phenomena not tied to energy neither related to microcosm. In particular, it is displayed that how the elements of the consolidated physical theories, arranged together using the ＂band structure＂, lead to a model for the distribution of speed in the universe that is essentially analogous to the distribution of energy in solids. The description is accompanied by references to the experimental data that sustain it, together with an overview of the possible development opportunities.展开更多
US News 2017年世界工科大学400强中俄罗斯只有1所：#376M．V．Lomonosov Moscow State University。
这个结果似明显地不合理，似反映USNews评价工科大学存在偏重科学忽视工程经验的问题。钱学森一生强调技术科学。对钱学森对科技科...US News 2017年世界工科大学400强中俄罗斯只有1所：#376M．V．Lomonosov Moscow State University。
这个结果似明显地不合理，似反映USNews评价工科大学存在偏重科学忽视工程经验的问题。钱学森一生强调技术科学。对钱学森对科技科学一贯一致的论述，我反复思考后，展开更多
文摘The Michael addition reactions of Z and E 4-methyl-benzaldoximes with propene were investigated theoretically by DFT method at B3LYP/6-31G* level.The calculation results show that both addition reactions are concerted processes accompanied by the migration of hydrogen from the atom oxygen to carbon.Both products Z and E nitrones have dipolar charge distributions and activities.Z isomer is more favorable in the reaction due to the barrier is lower.
基金supported by the Special Program of the Education Bureau of Shaanxi Province of China (No.08JK240)the Breeding Program for Provincial Level Key Research Base of Shaanxi University of Technology (No.SLGJD0806)
文摘In-situ Al2O3/TiAl composites were successfully synthesized from the starting powders of Ti, Al, TiO2 and Nb2O5. The oxidation behavior of the composites at 900℃ in static air was investigated. The results indicate that the composite samples present a much lower oxidation mass gain. Under long-time intensive oxidation exposure, the formed oxide scale is multi-layer. The formation of the outer TiO2 layer is fine and dense, the internal Al2O3 scale has good adhesiveness with the outer TiO2 scale, and the TiO2＋Al2O3 mixed layer forming the protective oxide scale is favorable for the improvement of oxidation resistance. It is believed that the incorporation of Al2O3 particulates into the metal matrix decreases the coefficient of thermal expansion of the substrate, and forms a local three-dimensional network structure that can hold the oxide scale. The formation of the oxide scale with finer particle size, stronger adherence, less micro-defects and slower growth rate can contribute to the improvement of oxidation resistance. Nb element plays an important role in reducing the internal oxidation action of the materials, restraining the growth of TiO2 crystals and promoting the stable formation of the Al2O3-riched layer, which is beneficial to improve the oxidation properties.
文摘This work is aimed at showing that the ＂band structure＂ of the energy distribution in solids which is a well-known model for electronic engineers and solid-state physics scientists is an efficacious description also for phenomena not tied to energy neither related to microcosm. In particular, it is displayed that how the elements of the consolidated physical theories, arranged together using the ＂band structure＂, lead to a model for the distribution of speed in the universe that is essentially analogous to the distribution of energy in solids. The description is accompanied by references to the experimental data that sustain it, together with an overview of the possible development opportunities.
