Chloroform and other volatile organic pollutants have garnered widespread attention from the public and researchers,because of their potential harm to the respiratory system,nervous system,skin,and eyes.However,resear...Chloroform and other volatile organic pollutants have garnered widespread attention from the public and researchers,because of their potential harm to the respiratory system,nervous system,skin,and eyes.However,research on chloroform vapor sensing is still in its early stages,primarily due to the lack of specific recognition motif.Here we report a mesoporous photonic crystal sensor incorporating carbon dots-based nanoreceptor(HMSS@CDs-PCs)for enhanced chloroform sensing.The colloidal PC packed with hollow mesoporous silica spheres provides an interconnected ordered macro-meso-hierarchical porous structure,ideal for rapid gas sensing utilizing the photonic bandgap shift as the readout signal.The as-synthesized CDs with pyridinic-N-oxide functional groups adsorbed in the hollow mesoporous silica spheres are found to not only serve as the chloroform adsorption sites,but also a molecular glue that prevents crack formation in the colloidal PC.The sensitivity of HMSS@CDs-PCs sensor is 0.79 nm ppm^(-1)and an impressively low limit of detection is 3.22 ppm,which are the best reported values in fast-response chloroform vapor sensor without multi-signal assistance.The positive response time is 7.5 s and the negative response time 9 s.Furthermore,relatively stable sensing can be maintained within a relative humidity of 20%-85%RH and temperature of 25-55℃.This study demonstrates that HMSS@CDs-PCs sensors have practical application potential in indoor and outdoor chloroform vapor detection.展开更多
Based on a new multi-source dataset (GLDP-V1.0) recently developed in China Meteorological Administration, we employed precipitation indices including percentile-based indices of light (below the 50th percentile), mod...Based on a new multi-source dataset (GLDP-V1.0) recently developed in China Meteorological Administration, we employed precipitation indices including percentile-based indices of light (below the 50th percentile), moderate (between the 50th and 90th percentile), and intense (above the 90th percentile) precipitation, maximum 1-day, 3-day, and 5-day precipitation amounts (RX1DAY, RX3DAY, and RX5DAY, respectively), and consecutive wet and dry days (CWDs and CDDs) to analyze variations in extreme precipitation events in the Hindu Kush Himalayan (HKH) during 1961e2012. The main results are presented as follows. Firstly, there was a significant increase in the amount of light and moderate precipitation and number of associated days over various parts of India and northern Tibetan Plateau during 1961e2012; but the intensity of light precipitation decreased significantly in the Hindu Kush and central India, and the regional average intensity also decreased. Secondly, the amount and frequency of intense precipitation mostly increased significantly on the Tibetan Plateau, but there was a heterogeneous change over the remainder of the HKH, and regional average annual intense precipitation amount and frequency significantly increased over the HKH during 1961e2012. Thirdly, regional average RX1DAY, RX3DAY, and RX5DAYall showed significant upward trends during 1961e2012, and there was a significant increased tendency of consecutive wet-days in most parts of the study region; however, trends of consecutive dry-days were mostly opposite to those of consecutive wet-days, with regional averaged consecutive dry-days showing no noticeable trend.展开更多
基金supported by the National Key Research and Development Program of China(No.2022YFB3205500)National Natural Science Foundation of China(Nos.U23A20360 and 62303192)QL wishes to thank Water Research Australia(WRA 1144/21)for funding support.
文摘Chloroform and other volatile organic pollutants have garnered widespread attention from the public and researchers,because of their potential harm to the respiratory system,nervous system,skin,and eyes.However,research on chloroform vapor sensing is still in its early stages,primarily due to the lack of specific recognition motif.Here we report a mesoporous photonic crystal sensor incorporating carbon dots-based nanoreceptor(HMSS@CDs-PCs)for enhanced chloroform sensing.The colloidal PC packed with hollow mesoporous silica spheres provides an interconnected ordered macro-meso-hierarchical porous structure,ideal for rapid gas sensing utilizing the photonic bandgap shift as the readout signal.The as-synthesized CDs with pyridinic-N-oxide functional groups adsorbed in the hollow mesoporous silica spheres are found to not only serve as the chloroform adsorption sites,but also a molecular glue that prevents crack formation in the colloidal PC.The sensitivity of HMSS@CDs-PCs sensor is 0.79 nm ppm^(-1)and an impressively low limit of detection is 3.22 ppm,which are the best reported values in fast-response chloroform vapor sensor without multi-signal assistance.The positive response time is 7.5 s and the negative response time 9 s.Furthermore,relatively stable sensing can be maintained within a relative humidity of 20%-85%RH and temperature of 25-55℃.This study demonstrates that HMSS@CDs-PCs sensors have practical application potential in indoor and outdoor chloroform vapor detection.
文摘Based on a new multi-source dataset (GLDP-V1.0) recently developed in China Meteorological Administration, we employed precipitation indices including percentile-based indices of light (below the 50th percentile), moderate (between the 50th and 90th percentile), and intense (above the 90th percentile) precipitation, maximum 1-day, 3-day, and 5-day precipitation amounts (RX1DAY, RX3DAY, and RX5DAY, respectively), and consecutive wet and dry days (CWDs and CDDs) to analyze variations in extreme precipitation events in the Hindu Kush Himalayan (HKH) during 1961e2012. The main results are presented as follows. Firstly, there was a significant increase in the amount of light and moderate precipitation and number of associated days over various parts of India and northern Tibetan Plateau during 1961e2012; but the intensity of light precipitation decreased significantly in the Hindu Kush and central India, and the regional average intensity also decreased. Secondly, the amount and frequency of intense precipitation mostly increased significantly on the Tibetan Plateau, but there was a heterogeneous change over the remainder of the HKH, and regional average annual intense precipitation amount and frequency significantly increased over the HKH during 1961e2012. Thirdly, regional average RX1DAY, RX3DAY, and RX5DAYall showed significant upward trends during 1961e2012, and there was a significant increased tendency of consecutive wet-days in most parts of the study region; however, trends of consecutive dry-days were mostly opposite to those of consecutive wet-days, with regional averaged consecutive dry-days showing no noticeable trend.
