模具表面改性日益受到人们重视。本文采用二维Particle-in-cell/Monte Carlo Collision模型对等离子体浸没离子注入处理凹模型腔内表面的鞘层动力学及均匀性进行了研究。考察了电压脉宽对鞘层中电势分布、离子的运动状态以及型腔内表面...模具表面改性日益受到人们重视。本文采用二维Particle-in-cell/Monte Carlo Collision模型对等离子体浸没离子注入处理凹模型腔内表面的鞘层动力学及均匀性进行了研究。考察了电压脉宽对鞘层中电势分布、离子的运动状态以及型腔内表面离子注入剂量、能量和角度的空间分布的影响。结果表明随着电压脉宽的增加,凹模型腔内表面的注入剂量不均匀性增加,同时注入到内表面的高能离子数目也增加。脉冲宽度变化对注入角度影响不大,离子以接近垂直的入射角度注入到型腔底部,而在侧壁上离子注入角度接近45°。当脉冲宽度较大时,发现少部分注入到侧壁上的离子以一定角度从下往上注入到样品表面,这是由于碰撞效应造成的。从能量和剂量的角度,存在一个合适的脉冲宽度,过大的脉宽会引起剂量不均匀性增加,同时离子注入能量也会下降。展开更多
模具表面改性对提高模具使用寿命和生产率有着十分重要的意义。本文采用二维Particle-in-cell/Monte Carlo colli-sion模型对不同气压下等离子体离子注入处理凹模型腔内表面的鞘层动力学进行研究。考察了气压变化对电势分布、离子运动...模具表面改性对提高模具使用寿命和生产率有着十分重要的意义。本文采用二维Particle-in-cell/Monte Carlo colli-sion模型对不同气压下等离子体离子注入处理凹模型腔内表面的鞘层动力学进行研究。考察了气压变化对电势分布、离子运动状态及凹模型腔内表面离子注入剂量、能量和角度分布的影响。计算结果表明随着气压的上升,凹模周围的鞘层厚度变薄;随气压上升,凹模型腔底部和顶部端面离子注入剂量和平均注入能量下降,在型腔侧壁上,离子注入剂量和平均注入能量先上升后下降。注入到型腔侧壁和凹模顶部端面上的离子平均注入角度随气压上升而趋向于垂直入射,型腔底部平均注入角度随气压上升略有增大。研究结果表明通过引入一定的碰撞(变化气压)来改善剂量和能量的均匀性是可行的。展开更多
In the present research,the NaF assisted plasma electrolytic oxidation(PEO)is designed to fabricate the high-content ZnO nanoparti-cles doped coating on AZ31B alloy.The microstructure,phase constituents and corrosion ...In the present research,the NaF assisted plasma electrolytic oxidation(PEO)is designed to fabricate the high-content ZnO nanoparti-cles doped coating on AZ31B alloy.The microstructure,phase constituents and corrosion behavior of the PEO coatings are investigated systematically.The results reveal that the introduction of NaF promotes the formation of MgF2 nanophases in the passivation layer on Mg alloy,decreasing the breakdown voltage and discharge voltage.As a result,the continuous arcing caused by high discharge voltage is alleviated.With the increasing of NaF content,the Zn content in the PEO coating is enhanced and the pore size in the coating is decreased correspondingly.Due to the high-content ZnO doping,the PEO coating protected AZ31B alloy demonstrates the better corrosion resistance.Compared with the bare AZ31B alloy,the high-content ZnO doped PEO coated sample shows an increased corrosion potential from-1.465 V to-1.008 V,a decreased corrosion current density from 3.043×10^(-5) A·cm^(-2) to 3.960×10^(-8) A·cm^(-2) and an increased charge transfer resistance from 1.213×10^(2) ohm·cm^(2) to 2.598×10^(5) ohm·cm^(2).Besides,the high-content ZnO doped PEO coated sample also has the excellent corrosion resistance in salt solution,exhibiting no obvious corrosion after more than 2000 h neutral salt spraying and 28 days’immersion testing.The improved corrosion resistance can be ascribed to the relative uniform distribution of ZnO in PEO coating which can transform to Zn(OH)2 and form a continuous protective layer along the corrosion interface.展开更多
文摘模具表面改性日益受到人们重视。本文采用二维Particle-in-cell/Monte Carlo Collision模型对等离子体浸没离子注入处理凹模型腔内表面的鞘层动力学及均匀性进行了研究。考察了电压脉宽对鞘层中电势分布、离子的运动状态以及型腔内表面离子注入剂量、能量和角度的空间分布的影响。结果表明随着电压脉宽的增加,凹模型腔内表面的注入剂量不均匀性增加,同时注入到内表面的高能离子数目也增加。脉冲宽度变化对注入角度影响不大,离子以接近垂直的入射角度注入到型腔底部,而在侧壁上离子注入角度接近45°。当脉冲宽度较大时,发现少部分注入到侧壁上的离子以一定角度从下往上注入到样品表面,这是由于碰撞效应造成的。从能量和剂量的角度,存在一个合适的脉冲宽度,过大的脉宽会引起剂量不均匀性增加,同时离子注入能量也会下降。
文摘模具表面改性对提高模具使用寿命和生产率有着十分重要的意义。本文采用二维Particle-in-cell/Monte Carlo colli-sion模型对不同气压下等离子体离子注入处理凹模型腔内表面的鞘层动力学进行研究。考察了气压变化对电势分布、离子运动状态及凹模型腔内表面离子注入剂量、能量和角度分布的影响。计算结果表明随着气压的上升,凹模周围的鞘层厚度变薄;随气压上升,凹模型腔底部和顶部端面离子注入剂量和平均注入能量下降,在型腔侧壁上,离子注入剂量和平均注入能量先上升后下降。注入到型腔侧壁和凹模顶部端面上的离子平均注入角度随气压上升而趋向于垂直入射,型腔底部平均注入角度随气压上升略有增大。研究结果表明通过引入一定的碰撞(变化气压)来改善剂量和能量的均匀性是可行的。
基金supported by the 2022 Shenzhen sustainable supporting funds for colleges and universities(20220810143642004)Shenzhen Basic Research Project(JCYJ20200109144608205 and JCYJ20210324120001003)+5 种基金Peking University Shenzhen Graduate School Research Startup Fund of Introducing Talent(No.1270110273)Shenzhen postdoctoral research fund project after outbound(No.2129933651)Shenzhen-Hong Kong Research and Development Fund(No.SGDX20201103095406024)City University of Hong Kong Strategic Research Grants(SRG)(Nos.7005264 and 7005505)Guangdong-Hong Kong Technology Cooperation Funding Scheme(TCFS)(No.GHP/085/18SZ)IER Foundation(IERF2020001 and IERF2019002).
文摘In the present research,the NaF assisted plasma electrolytic oxidation(PEO)is designed to fabricate the high-content ZnO nanoparti-cles doped coating on AZ31B alloy.The microstructure,phase constituents and corrosion behavior of the PEO coatings are investigated systematically.The results reveal that the introduction of NaF promotes the formation of MgF2 nanophases in the passivation layer on Mg alloy,decreasing the breakdown voltage and discharge voltage.As a result,the continuous arcing caused by high discharge voltage is alleviated.With the increasing of NaF content,the Zn content in the PEO coating is enhanced and the pore size in the coating is decreased correspondingly.Due to the high-content ZnO doping,the PEO coating protected AZ31B alloy demonstrates the better corrosion resistance.Compared with the bare AZ31B alloy,the high-content ZnO doped PEO coated sample shows an increased corrosion potential from-1.465 V to-1.008 V,a decreased corrosion current density from 3.043×10^(-5) A·cm^(-2) to 3.960×10^(-8) A·cm^(-2) and an increased charge transfer resistance from 1.213×10^(2) ohm·cm^(2) to 2.598×10^(5) ohm·cm^(2).Besides,the high-content ZnO doped PEO coated sample also has the excellent corrosion resistance in salt solution,exhibiting no obvious corrosion after more than 2000 h neutral salt spraying and 28 days’immersion testing.The improved corrosion resistance can be ascribed to the relative uniform distribution of ZnO in PEO coating which can transform to Zn(OH)2 and form a continuous protective layer along the corrosion interface.
