In this study,two series of cerium zirconium mixed oxides CeZrLaPrOwere prepared under traditional co-precipitation and oxidation co-precipitation methods respectively. The physicochemical properties of the samples we...In this study,two series of cerium zirconium mixed oxides CeZrLaPrOwere prepared under traditional co-precipitation and oxidation co-precipitation methods respectively. The physicochemical properties of the samples were compared under these two methods and assessed by XRD,Raman,BET,TEM,HTPR,OSC,XPS and catalysts measurements. The formation of homogeneity phase structure can be facilitated by changing the precipitating properties of Ce3+ under oxidation coprecipitation method, which is helpful to enhance the homogeneity of Ce and Zr at atomic level.What’s more, it is conducive to remove impurities Na~+ and Cl~-by oxidation co-precipitation with hydrogen peroxide. The catalysts activities are related to both the redox properties and the textural properties of mixed oxides. The Pd-only TWCs supported on the CZLP-H-F exhibits better catalytic performance and thermal stability with wider air/fuel ratio operation window, lower light-off and full conversion temperatures of CHand NO. The homogeneity of phase structure for cerium zirconium mixed oxide can be predicted and deduced from detecting the atomic distribution uniformity of its precursor. So this work not only provides insights into the mechanisms for phase segregation of cerium zirconium mixed oxide, but also provides a guidance to improve homogeneity of cerium zirconium mixed oxide by adding additives.展开更多
The Neogene Terror Rift in the Antarctic Victoria Land Basin(VLB)of the Ross Sea,Antarctica,is composed of the Discovery Graben and the Lee Arch.Many Neogene volcanoes are aligned in the north-south direction in the s...The Neogene Terror Rift in the Antarctic Victoria Land Basin(VLB)of the Ross Sea,Antarctica,is composed of the Discovery Graben and the Lee Arch.Many Neogene volcanoes are aligned in the north-south direction in the southern VLB,belonging to the McMurdo Volcanic Group.However,due to multiple glaciations and limited seismic data,the volcanic processes are still unclear in the northern VLB,especially in the Terror Rift.Multichannel seismic profiles were collected at the VLB from the 32nd Chinese National Antarctic Research Expedition(CHINARE).We utilized four seismic profiles from the CHINARE and additional historical profiles,along with gravity and magnetic anomalies,to analyze faults and stratigraphic characteristics in the northern Terror Rift and volcanism in the VLB.Negative flower structures found in the northern Terror Rift suggest that the Terror Rift was affected by dextral strike-slip faults extending from the northern Victoria Land(NVL).After the initial orthogonal tension,the rift transited into an oblique extension,forming a set of downward concaving normal faults and accommodation zones in the Terror Rift.On the Lee Arch,several imbricated normal faults formed and converged into a detachment fault.Under gravitational forces,the strata bent upward and formed a rollover anticline.Many deep faults and thin strata subjected to erosion facilitated volcanic activity.A brittle volcanic region in the VLB was affected by dextral strike-slip movements and east-west extension,resulting in two Neogene volcanic chains that connect three igneous provinces in the VLB:the Hallett,Melbourne,and Erebus Provinces.These two chains contain mud volcanoes with magnetic nuclei,volcanic intrusions,and late-stage volcanic eruptions.Volcanisms have brought about opposite polarities of magnetic anomalies in Antarctica,indicating the occurrence of multiple volcanic activities.展开更多
为把握残疾污名的国际研究热点,利用Citespace软件对2001—2021年间Web of Science数据库中的447篇文献进行可视化分析。分析结果显示,教育学、心理学和社会学是污名研究的主要学科领域;四大研究热点包括不同障碍类别的污名研究、由自...为把握残疾污名的国际研究热点,利用Citespace软件对2001—2021年间Web of Science数据库中的447篇文献进行可视化分析。分析结果显示,教育学、心理学和社会学是污名研究的主要学科领域;四大研究热点包括不同障碍类别的污名研究、由自我延伸至他人的污名影响研究、公众污名研究和全程特征的污名研究;研究发展趋势经历了从关注污名的外部歧视标签到内部形成机制再到污名干预的变化。该分析结果为破解残疾污名困境,创设“平等、参与、共享”的社会环境提供了启示。展开更多
基金the financial supports from Grirem Advanced Materials Co.,Ltd.
文摘In this study,two series of cerium zirconium mixed oxides CeZrLaPrOwere prepared under traditional co-precipitation and oxidation co-precipitation methods respectively. The physicochemical properties of the samples were compared under these two methods and assessed by XRD,Raman,BET,TEM,HTPR,OSC,XPS and catalysts measurements. The formation of homogeneity phase structure can be facilitated by changing the precipitating properties of Ce3+ under oxidation coprecipitation method, which is helpful to enhance the homogeneity of Ce and Zr at atomic level.What’s more, it is conducive to remove impurities Na~+ and Cl~-by oxidation co-precipitation with hydrogen peroxide. The catalysts activities are related to both the redox properties and the textural properties of mixed oxides. The Pd-only TWCs supported on the CZLP-H-F exhibits better catalytic performance and thermal stability with wider air/fuel ratio operation window, lower light-off and full conversion temperatures of CHand NO. The homogeneity of phase structure for cerium zirconium mixed oxide can be predicted and deduced from detecting the atomic distribution uniformity of its precursor. So this work not only provides insights into the mechanisms for phase segregation of cerium zirconium mixed oxide, but also provides a guidance to improve homogeneity of cerium zirconium mixed oxide by adding additives.
基金supported by the Impact and Response of Antarctic Seas to Climate Change Project (IRASCC01-03-01)Hainan Naturtal Science Foundation Inovative Research Team Project (421CXTD441)the National Natural Science Foundation of China (Nos. 42176067, 41576069, 42176055, 41776189 and 41906197)
文摘The Neogene Terror Rift in the Antarctic Victoria Land Basin(VLB)of the Ross Sea,Antarctica,is composed of the Discovery Graben and the Lee Arch.Many Neogene volcanoes are aligned in the north-south direction in the southern VLB,belonging to the McMurdo Volcanic Group.However,due to multiple glaciations and limited seismic data,the volcanic processes are still unclear in the northern VLB,especially in the Terror Rift.Multichannel seismic profiles were collected at the VLB from the 32nd Chinese National Antarctic Research Expedition(CHINARE).We utilized four seismic profiles from the CHINARE and additional historical profiles,along with gravity and magnetic anomalies,to analyze faults and stratigraphic characteristics in the northern Terror Rift and volcanism in the VLB.Negative flower structures found in the northern Terror Rift suggest that the Terror Rift was affected by dextral strike-slip faults extending from the northern Victoria Land(NVL).After the initial orthogonal tension,the rift transited into an oblique extension,forming a set of downward concaving normal faults and accommodation zones in the Terror Rift.On the Lee Arch,several imbricated normal faults formed and converged into a detachment fault.Under gravitational forces,the strata bent upward and formed a rollover anticline.Many deep faults and thin strata subjected to erosion facilitated volcanic activity.A brittle volcanic region in the VLB was affected by dextral strike-slip movements and east-west extension,resulting in two Neogene volcanic chains that connect three igneous provinces in the VLB:the Hallett,Melbourne,and Erebus Provinces.These two chains contain mud volcanoes with magnetic nuclei,volcanic intrusions,and late-stage volcanic eruptions.Volcanisms have brought about opposite polarities of magnetic anomalies in Antarctica,indicating the occurrence of multiple volcanic activities.
文摘为把握残疾污名的国际研究热点,利用Citespace软件对2001—2021年间Web of Science数据库中的447篇文献进行可视化分析。分析结果显示,教育学、心理学和社会学是污名研究的主要学科领域;四大研究热点包括不同障碍类别的污名研究、由自我延伸至他人的污名影响研究、公众污名研究和全程特征的污名研究;研究发展趋势经历了从关注污名的外部歧视标签到内部形成机制再到污名干预的变化。该分析结果为破解残疾污名困境,创设“平等、参与、共享”的社会环境提供了启示。
