The self-monitoring application of asphalt concrete containing graphite and carbon fibers using indirect tensile test and wheel rolling test were introduced. The experiment results indicate that this kind of pitch-bas...The self-monitoring application of asphalt concrete containing graphite and carbon fibers using indirect tensile test and wheel rolling test were introduced. The experiment results indicate that this kind of pitch-based composite is effective for strain/stress self-monitoring. In the indirect tensile test, for a completely conductive asphalt concrete specimen, the piezoresistivity was very weak and slightly positive, which meant the resistivity increase with the increment of tensile strain at all stress/strain amplitudes, with the gage factor as high as 6. The strain self-sensing ability was superior in the case of higher graphite content. However, when the conductive concrete was embedded into common asphalt concrete specimen as a partial structure function, the piezoresistivity was positive at all stress/strain amplitudes and with the gage factor of 13, which was much higher than that of completely conductive specimen. Thus, the strain self-sensing ability was superior when conductive asphalt concrete was taken in as a partial structure function. In the wheel-rolling test, the piezoresistivity was highly positive. At any stress amplitude, the piezoresistivity was strong, with the gage factor as high as 100, which was higher for a stress amplitude of 0.7 MPa than that of 0.5 MPa.展开更多
Microstructure of solid phase reduction on manganese oxide ore fines containing coal （MOOFCC） is one of important kinetics conditions of influencing microwave heating. On condition thai an atomic molar ratio of ro ...Microstructure of solid phase reduction on manganese oxide ore fines containing coal （MOOFCC） is one of important kinetics conditions of influencing microwave heating. On condition thai an atomic molar ratio of ro ： rc in MOOFCC is 1 ： 1.06 as well as a molecular molar ratio of rSiO2： rCaO is 1 ： 1.28, 1 kg of MOOFCC is heated by microwave to reach 1 000-1 300℃ and hold different time respectively. Experiments show that the metal phase takes the iron-based metal compounds containing manganese as the main content. The manganese content of metal phase increases with the xise of temperature. The particle size of the metal phase is within the range from 0. 01 to 0.05 mm. MO2 phase in the stuff is entirely changed into MnO phase and the slag phase is mainly composed of wollastonite and manganese olivine. The stuff reduced is loose and massive as a whole and its porosity is from 30% to 45%. The low softening-melting property and the low density of the stuff impact, to some degree, the solid phase reduction of powder by microwave heating.展开更多
The results of field observation carried out in May 2003 were used to examine pH and total alkalinity behaviors in the Changjiang Estuary. It was showed that pH and total alkalinity took on clear spatial variations in...The results of field observation carried out in May 2003 were used to examine pH and total alkalinity behaviors in the Changjiang Estuary. It was showed that pH and total alkalinity took on clear spatial variations in values with the minima in the low salinity region. Like salinity, transect distributions of pH and total alkalinity （TA） in a downriver direction had a sharp gradient each. These gradients appeared in such a sequence that the TA gradient was earlier than salinity and pH gradients, and the salinity gradient was earlier than the pH gradient. These distribution characteristics seemed to be strongly influenced by the mixing process of freshwater and seawater, for both pH and total alkalinity had significant linear relationships with salinity and temperature. For pH, phytoplankton activities also had a significant impact upon its spatial distribution. During a period of 48 h, pH and total alkalinity changed within wide ranges for every layer of the two anchor stations, namely, Stas 13 and 20, which were located at the mixed water mass and seawater mass, respectively. For both Stas 13 and 20, pH and TA fluctuation of every layer could be very wide during a 4 h period. As a whole, the data of the two anchor stations showed that neither variations in salinity and temperature nor phytoplankton activities were the main factors strongly influencing the total alkalinity temporal variability on a small time scale. The data of Sta. 20 implied that both salinity variation and phytoplankton activities had a significant influence on pH temporal variability, but the same conclusion could not be drawn from the data of Sta. 13.展开更多
A mechanical model to control the top-coal deformation is established in accordance with the structural characters of the gob-side entry surrounding rock for the fully-mechanic top-coal caving; the analytical solution...A mechanical model to control the top-coal deformation is established in accordance with the structural characters of the gob-side entry surrounding rock for the fully-mechanic top-coal caving; the analytical solution of top coal roof-sag curve is deduced with Winkler elastic foundation beam model. By means of a calculating and analytic program, the top coal roof-sag values are calculated under the conditions of different supporting intensities, widths of narrow pillars and stiffness of top coal; meanwhile, the relationship between the roof-sag values and supporting intensity, width of narrow pillars and stiffness of top coal is analyzed as well. With the actual situation of the gob-side entry taken into consideration, the parameters of top-coal control are determined and a supporting plan is proposed for the top-coal control,which is proved to be reliable and effective by on-site verification. Some theoretical guidance and advice are put forward for the top-coal deformation control in gob-side entry for fully mechanized top-coal caving face.展开更多
Rock residual strength,as an important input parameter,plays an indispensable role in proposing the reasonable and scientific scheme about stope design,underground tunnel excavation and stability evaluation of deep ch...Rock residual strength,as an important input parameter,plays an indispensable role in proposing the reasonable and scientific scheme about stope design,underground tunnel excavation and stability evaluation of deep chambers.Therefore,previous residual strength models of rocks established were reviewed.And corresponding related problems were stated.Subsequently,starting from the effects of bedding and whole life-cycle evolution process,series of triaxial mechanical tests of deep bedded sandstone with five bedding angles were conducted under different confining pressures.Then,six residual strength models considering the effects of bedding and whole life-cycle evolution process were established and evaluated.Finally,a cohesion loss model for determining residual strength of deep bedded sandstone was verified.The results showed that the effects of bedding and whole life-cycle evolution process had both significant influences on the evolution characteristic of residual strength of deep bedded sandstone.Additionally,residual strength parameters:residual cohesion and residual internal friction angle of deep bedded sandstone were not constant,which both significantly changed with increasing bedding angle.Besides,the cohesion loss model was the most suitable for determining and estimating the residual strength of bedded rocks,which could provide more accurate theoretical guidance for the stability control of deep chambers.展开更多
At present,the surrounding rock of the deep mine roadway is prone to post-peak stress under the action of high stress,and secondary rock burst disaster is prone to occur under complex stress disturbance.According to i...At present,the surrounding rock of the deep mine roadway is prone to post-peak stress under the action of high stress,and secondary rock burst disaster is prone to occur under complex stress disturbance.According to incomplete statistics,as of 2023,80%of coal mine rock bursts accidents in China occur in mining roadway.In view of this phenomenon,the cyclic impact test of post-peak sandstone is designed,focusing on the post-peak stress state of sandstone,and exploring the post-peak dynamic response of sandstone.The post-peak sandstone specimens were prepared by a uniaxial compressor,and then cyclic impact tests were carried out on the post-peak sandstone under different coaxial pressure conditions by an improved separated Hopkinson equipment.The results show that:1)The number of impact times required for sandstone failure after peak decreased with the increase of axial pressure,indicating that the impact tendency of sandstone after peak decreased under lower axial pressure.On the contrary,the post-peak sandstone had strong impact tendency under higher axial pressure;2)The higher the axial pressure,the lower the dynamic strength of the post-peak sandstone,indicating that the axial pressure promoted the failure process of the post peak sandstone;3)It was a nonlinear evolution of a quadratic polynomial function between the dissipation-energy release rate and axial pressure;4)Shear failure occurred mainly in post-peak impact sandstone with the increased axial pressure,and the composite failure of intergranular failure and transgranular failure changed to single intergranular failure at the microscopic level.The research shows that when the roadway surrounding rock was in the post-peak stress state,reducing the static stress was the key to prevent the secondary ground pressure disaster.The research results provide a theoretical basis for the prevention and control of roadway rock burst disaster under high ground stress environment,and promote the research and exploration of post-peak mechanical properties of coal and rock.展开更多
A genus within the family Douvillinidae of the order Strophomenida from the Erdaogou Memberof the Xibiehe Formation in the Early Devonian of central Jilin has been re-examined, with considerationgiven to the 56 specim...A genus within the family Douvillinidae of the order Strophomenida from the Erdaogou Memberof the Xibiehe Formation in the Early Devonian of central Jilin has been re-examined, with considerationgiven to the 56 specimens collected and described by Liu and Huang (1977). Based on its distinct externalornamentation and internal characteristics, it has been classified as Cymostrophia (Protocymostrophia). It isconcluded that the three specices described by Liu and Huang (1977), Idioglyptus alatus, I. semicircularis,I. subquadratus, as well as the Mesodouvillina jilinensis Su, 1980 should be considered synonyms and benamed Cymostrophia (Protocymostrophia) alatus (Liu) Li.展开更多
This study addresses the enhanced cycling stability of zinc-based flow batteries through a synergistic strategy integrating a vine-derived porous carbon framework(3D VPCF)with nicotinamide(NAM)in alkaline Zn-Fe hybrid...This study addresses the enhanced cycling stability of zinc-based flow batteries through a synergistic strategy integrating a vine-derived porous carbon framework(3D VPCF)with nicotinamide(NAM)in alkaline Zn-Fe hybrid liquid-solid flow batteries.By introducing 0.15 mol/L NAM to suppress zinc dendrite growth and regulate deposition behavior,combined with 0.05 mol/L ZnO additives for optimized nucleation and electrolyte conductivity,we achieved enhanced reversibility of zinc deposition/dissolution and interfacial stability.The system exhibits stable charge/discharge plateaus at 5 mA/cm^(2)(non-normalized to electrode area),demonstrating 99.9%capacity retention over 1000 cycles.This work provides an innovative pathway for developing stable zinc-based energy storage systems.展开更多
文摘尽管长波红外成像技术在陆地遥感、天文学等应用中至关重要,但其面临着来自压倒性热背景辐射的根本性挑战。这种背景光子通量常常将传统探测器推向其背景限制性能(Background-Limited Performance,BLIP)的极限。此时主要的限制因素并非探测器固有的噪声,而是背景本身的散粒噪声。本文论证了一个关键的分类,以区分两种表面相似但本质迥异的探测架构——差分探测器和微分探测器。根据探测器的应用和实现途径可知,传统差分探测器的背景光电流为可探测的信号差异设置了一个由背景决定的阈值,而微分探测器则是一种在物理感知层面直接对目标物理量的差异进行测量的器件:只有微弱的差值信号被积分,导致极大量的累加采样,因此可将信噪比提升至前所未有的水平。特别介绍了基于量子阱红外光电探测器(Quantum Well Infrared Photodetector,QWIP)的微分探测技术路径。QWIP以其极低的暗电流、精准的电学可控性和内禀的光谱选择性,为实现高性能长波红外微分探测器提供了理想的物理基础,并已在实验中取得显著进展。最后利用费雪信息理论和克拉默--拉奥约束为微分探测器提供了严格的理论支撑。
基金the Outstanding Youth Foundation of Hubei Province(No.2004ABB019)Program for New Century Excellent Talents in University,China(No.NCET-05-0665)
文摘The self-monitoring application of asphalt concrete containing graphite and carbon fibers using indirect tensile test and wheel rolling test were introduced. The experiment results indicate that this kind of pitch-based composite is effective for strain/stress self-monitoring. In the indirect tensile test, for a completely conductive asphalt concrete specimen, the piezoresistivity was very weak and slightly positive, which meant the resistivity increase with the increment of tensile strain at all stress/strain amplitudes, with the gage factor as high as 6. The strain self-sensing ability was superior in the case of higher graphite content. However, when the conductive concrete was embedded into common asphalt concrete specimen as a partial structure function, the piezoresistivity was positive at all stress/strain amplitudes and with the gage factor of 13, which was much higher than that of completely conductive specimen. Thus, the strain self-sensing ability was superior when conductive asphalt concrete was taken in as a partial structure function. In the wheel-rolling test, the piezoresistivity was highly positive. At any stress amplitude, the piezoresistivity was strong, with the gage factor as high as 100, which was higher for a stress amplitude of 0.7 MPa than that of 0.5 MPa.
基金Item Sponsored by National Natural Science Foundation of China (50674069)
文摘Microstructure of solid phase reduction on manganese oxide ore fines containing coal （MOOFCC） is one of important kinetics conditions of influencing microwave heating. On condition thai an atomic molar ratio of ro ： rc in MOOFCC is 1 ： 1.06 as well as a molecular molar ratio of rSiO2： rCaO is 1 ： 1.28, 1 kg of MOOFCC is heated by microwave to reach 1 000-1 300℃ and hold different time respectively. Experiments show that the metal phase takes the iron-based metal compounds containing manganese as the main content. The manganese content of metal phase increases with the xise of temperature. The particle size of the metal phase is within the range from 0. 01 to 0.05 mm. MO2 phase in the stuff is entirely changed into MnO phase and the slag phase is mainly composed of wollastonite and manganese olivine. The stuff reduced is loose and massive as a whole and its porosity is from 30% to 45%. The low softening-melting property and the low density of the stuff impact, to some degree, the solid phase reduction of powder by microwave heating.
基金This study was supported by the Qingdao Special Program for Leading Scientists under contract No.04-3-JJ-03the Knowledge Innovation Program of the Chinese Academy of Sciences under contract No.KZCX1-SW-01-08the“100 Talents Project”of the Chinese Academy of Sciences and the National Science Foundation for Outstanding Young Scientists of China under contract No.49925614.
文摘The results of field observation carried out in May 2003 were used to examine pH and total alkalinity behaviors in the Changjiang Estuary. It was showed that pH and total alkalinity took on clear spatial variations in values with the minima in the low salinity region. Like salinity, transect distributions of pH and total alkalinity （TA） in a downriver direction had a sharp gradient each. These gradients appeared in such a sequence that the TA gradient was earlier than salinity and pH gradients, and the salinity gradient was earlier than the pH gradient. These distribution characteristics seemed to be strongly influenced by the mixing process of freshwater and seawater, for both pH and total alkalinity had significant linear relationships with salinity and temperature. For pH, phytoplankton activities also had a significant impact upon its spatial distribution. During a period of 48 h, pH and total alkalinity changed within wide ranges for every layer of the two anchor stations, namely, Stas 13 and 20, which were located at the mixed water mass and seawater mass, respectively. For both Stas 13 and 20, pH and TA fluctuation of every layer could be very wide during a 4 h period. As a whole, the data of the two anchor stations showed that neither variations in salinity and temperature nor phytoplankton activities were the main factors strongly influencing the total alkalinity temporal variability on a small time scale. The data of Sta. 20 implied that both salinity variation and phytoplankton activities had a significant influence on pH temporal variability, but the same conclusion could not be drawn from the data of Sta. 13.
基金funded by the National Natural Science Foundation of China(No.51374201,51323004)the State Key Development Program for Basic Research of China(No.2013CB227900)the College Student’s Program for Innovation of China University of Mining and Technology of China(No.201507)
文摘A mechanical model to control the top-coal deformation is established in accordance with the structural characters of the gob-side entry surrounding rock for the fully-mechanic top-coal caving; the analytical solution of top coal roof-sag curve is deduced with Winkler elastic foundation beam model. By means of a calculating and analytic program, the top coal roof-sag values are calculated under the conditions of different supporting intensities, widths of narrow pillars and stiffness of top coal; meanwhile, the relationship between the roof-sag values and supporting intensity, width of narrow pillars and stiffness of top coal is analyzed as well. With the actual situation of the gob-side entry taken into consideration, the parameters of top-coal control are determined and a supporting plan is proposed for the top-coal control,which is proved to be reliable and effective by on-site verification. Some theoretical guidance and advice are put forward for the top-coal deformation control in gob-side entry for fully mechanized top-coal caving face.
基金Projects(2024YFC3013801,2022YFC3004602)supported by the National Key R&D Program of ChinaProjects(U23B2093,52034009)supported by the National Natural Science Foundation of China。
文摘Rock residual strength,as an important input parameter,plays an indispensable role in proposing the reasonable and scientific scheme about stope design,underground tunnel excavation and stability evaluation of deep chambers.Therefore,previous residual strength models of rocks established were reviewed.And corresponding related problems were stated.Subsequently,starting from the effects of bedding and whole life-cycle evolution process,series of triaxial mechanical tests of deep bedded sandstone with five bedding angles were conducted under different confining pressures.Then,six residual strength models considering the effects of bedding and whole life-cycle evolution process were established and evaluated.Finally,a cohesion loss model for determining residual strength of deep bedded sandstone was verified.The results showed that the effects of bedding and whole life-cycle evolution process had both significant influences on the evolution characteristic of residual strength of deep bedded sandstone.Additionally,residual strength parameters:residual cohesion and residual internal friction angle of deep bedded sandstone were not constant,which both significantly changed with increasing bedding angle.Besides,the cohesion loss model was the most suitable for determining and estimating the residual strength of bedded rocks,which could provide more accurate theoretical guidance for the stability control of deep chambers.
基金Projects(U23B2093,52034009)supported by the National Natural Science Foundation of ChinaProject(2022YFC3004602)supported by the National Key Research and Development Program of ChinaProject(BBJ2024009)supported by the Fundamental Research Funds for the Central Universities,China。
文摘At present,the surrounding rock of the deep mine roadway is prone to post-peak stress under the action of high stress,and secondary rock burst disaster is prone to occur under complex stress disturbance.According to incomplete statistics,as of 2023,80%of coal mine rock bursts accidents in China occur in mining roadway.In view of this phenomenon,the cyclic impact test of post-peak sandstone is designed,focusing on the post-peak stress state of sandstone,and exploring the post-peak dynamic response of sandstone.The post-peak sandstone specimens were prepared by a uniaxial compressor,and then cyclic impact tests were carried out on the post-peak sandstone under different coaxial pressure conditions by an improved separated Hopkinson equipment.The results show that:1)The number of impact times required for sandstone failure after peak decreased with the increase of axial pressure,indicating that the impact tendency of sandstone after peak decreased under lower axial pressure.On the contrary,the post-peak sandstone had strong impact tendency under higher axial pressure;2)The higher the axial pressure,the lower the dynamic strength of the post-peak sandstone,indicating that the axial pressure promoted the failure process of the post peak sandstone;3)It was a nonlinear evolution of a quadratic polynomial function between the dissipation-energy release rate and axial pressure;4)Shear failure occurred mainly in post-peak impact sandstone with the increased axial pressure,and the composite failure of intergranular failure and transgranular failure changed to single intergranular failure at the microscopic level.The research shows that when the roadway surrounding rock was in the post-peak stress state,reducing the static stress was the key to prevent the secondary ground pressure disaster.The research results provide a theoretical basis for the prevention and control of roadway rock burst disaster under high ground stress environment,and promote the research and exploration of post-peak mechanical properties of coal and rock.
基金Supported by the National Natural Science Foundation of China Nos.41702011 and 41372019.
文摘A genus within the family Douvillinidae of the order Strophomenida from the Erdaogou Memberof the Xibiehe Formation in the Early Devonian of central Jilin has been re-examined, with considerationgiven to the 56 specimens collected and described by Liu and Huang (1977). Based on its distinct externalornamentation and internal characteristics, it has been classified as Cymostrophia (Protocymostrophia). It isconcluded that the three specices described by Liu and Huang (1977), Idioglyptus alatus, I. semicircularis,I. subquadratus, as well as the Mesodouvillina jilinensis Su, 1980 should be considered synonyms and benamed Cymostrophia (Protocymostrophia) alatus (Liu) Li.
基金Project(22275074)supported by the National Natural Science Foundation of China。
文摘This study addresses the enhanced cycling stability of zinc-based flow batteries through a synergistic strategy integrating a vine-derived porous carbon framework(3D VPCF)with nicotinamide(NAM)in alkaline Zn-Fe hybrid liquid-solid flow batteries.By introducing 0.15 mol/L NAM to suppress zinc dendrite growth and regulate deposition behavior,combined with 0.05 mol/L ZnO additives for optimized nucleation and electrolyte conductivity,we achieved enhanced reversibility of zinc deposition/dissolution and interfacial stability.The system exhibits stable charge/discharge plateaus at 5 mA/cm^(2)(non-normalized to electrode area),demonstrating 99.9%capacity retention over 1000 cycles.This work provides an innovative pathway for developing stable zinc-based energy storage systems.
