In coal mining on a high-pressure Ordovician limestone aquifer,grouting materials should have sufficient mechanical properties,particularly strong interfacial bonding performance to address stress concentration at the...In coal mining on a high-pressure Ordovician limestone aquifer,grouting materials should have sufficient mechanical properties,particularly strong interfacial bonding performance to address stress concentration at the grout-limestone interface induced by rock stress disturbances during mining.In this study,graphene oxide(GO)was integrated into cement-polyacrylate composite grout to improve its interfacial bonding.First,four-point bending tests were conducted,and the Monte Carlo method combined with the simplex search algorithm was employed to determine the variations in shear cohesion and static friction parameters.The results reveal that GO can significantly increase both the tensile and shear cohesion of the grout-limestone interface,but minimally affects the interfacial friction coefficient.Second,nuclear magnetic resonance(NMR)and scanning electron microscopy(SEM)tests were performed.The results indicate that GO nanosheets result in a squamaceous microstructure of the grout consolidation mass,increasing the adhesion of the grout-limestone interface.Moreover,spiny Aft(ettringite)clusters can be induced in limestone fracture surfaces by GO,which could serve as anchors for limestone and grout consolidation mass.展开更多
Robust, ultra-flexible, and multifunctional MXene-basedelectromagnetic interference (EMI) shielding nanocomposite filmsexhibit enormous potential for applications in artificial intelligence,wireless telecommunication,...Robust, ultra-flexible, and multifunctional MXene-basedelectromagnetic interference (EMI) shielding nanocomposite filmsexhibit enormous potential for applications in artificial intelligence,wireless telecommunication, and portable/wearable electronic equipment.In this work, a nacre-inspired multifunctional heterocyclic aramid(HA)/MXene@polypyrrole (PPy) (HMP) nanocomposite paper withlarge-scale, high strength, super toughness, and excellent tolerance tocomplex conditions is fabricated through the strategy of HA/MXenehydrogel template-assisted in-situ assembly of PPy. Benefiting from the"brick-and-mortar" layered structure and the strong hydrogen-bondinginteractions among MXene, HA, and PPy, the paper exhibits remarkable mechanical performances, including high tensile strength (309.7 MPa),outstanding toughness (57.6 MJ m−3), exceptional foldability, and structural stability against ultrasonication. By using the template effect ofHA/MXene to guide the assembly of conductive polymers, the synthesized paper obtains excellent electronic conductivity. More importantly,the highly continuous conductive path enables the nanocomposite paper to achieve a splendid EMI shielding effectiveness (EMI SE) of 54.1 dBat an ultra-thin thickness (25.4 μm) and a high specific EMI SE of 17,204.7 dB cm2g−1. In addition, the papers also have excellent applicationsin electromagnetic protection, electro-/photothermal de-icing, thermal therapy, and fire safety. These findings broaden the ideas for developinghigh-performance and multifunctional MXene-based films with enormous application potential in EMI shielding and thermal management.展开更多
To improve the yield and quality of rice grown on saline-alkali soil,a meta-analysis combined with micro-district experimental studies was conducted in China to examine the impact of humic acidbased organic fertilizer...To improve the yield and quality of rice grown on saline-alkali soil,a meta-analysis combined with micro-district experimental studies was conducted in China to examine the impact of humic acidbased organic fertilizer and chemical fertilizer on rice yield and quality.This study employed a two-factor fully randomized experimental design,incorporating four levels of humic acid(F0,0.0 g/pot;F1,4.8 g/pot;F2,12.0 g/pot;and F3,19.2 g/pot)and three levels of chemical fertilizer(A1,full conventional dosage;A2,85% of conventional dosage;and A3,70% of conventional dosage).The meta-analysis revealed that the application of organic fertilizer(at a rate of 1500‒3000 kg/hm^(2))combined with chemical fertilizer had a significantly positive effect on the theoretical yield,tiller number,partial factor productivity,and SPAD value of rice.Temperature,organic fertilizer application,and chemical fertilizer levels were identified as critical factors affecting rice yield.The micro-experiments demonstrated that the application of humic acid organic fertilizer with treatment F3 significantly elevated the SPAD value at the full heading and grain filling stages.Increased panicle number and seed-setting rate were the main contributors to the rise in yield,with the F3 treatment yielding the highest overall.The effective leaf area,high-efficiency leaf area,and dry matter accumulation in rice treated with F3 were all higher compared with the F0 treatment.Our findings indicated that the addition of humic acid organic fertilizer can markedly improve the partial factor productivity and agronomic efficiency of rice.In conclusion,the application of F3 organic fertilizer combined with A3 chemical fertilizer(F3A3)significantly increased the yield of saline-alkali rice,which was 6.62% higher than that of the F0A1 treatment,thereby validating the meta-analysis outcomes.We propose that the combined use of humic acid organic fertilizer and chemical fertilizer can promote the growth of rice in saline-alkali soils.Consequently,these management practices provide a means to foster the green and healthy development of rice in saline-alkali regions across China.展开更多
Due to severe mass transfer limitations,the remediation efficiency of low-permeability contaminated sites often fails to meet expectations.Hydraulic fracturing technology has been utilized to enhance amendment deliver...Due to severe mass transfer limitations,the remediation efficiency of low-permeability contaminated sites often fails to meet expectations.Hydraulic fracturing technology has been utilized to enhance amendment delivery,but the influence of soil heterogeneity is commonly overlooked.To address this issue,this study develops a numerical model to simulate the enhanced transport of amendments,incorporating convection,diffusion,adsorption,and degradation processes.Within the model,random permeability fields are generated based on geostatistical methods to explore how soil heterogeneity affects amendment injection efficiency,distribution characteristics,and the underlying physical mechanisms.The results indicate that(1)soil heterogeneity significantly reduces the amendment injection efficiency,with stronger heterogeneity correlating to lower efficiency,(2)soil heterogeneity markedly alters the amendment distribution characteristics,leading to the formation of localized“nodes”,(3)the mechanism by which heterogeneity reduces injection efficiency involves decreasing the density of preferential flow paths in the soil,and(4)the adverse effects of heterogeneity can be mitigated by employing pressure compensation or adjusting well spacing.展开更多
The Chinese perspective is an open and evolving theoretical system.From a spatiotemporal viewpoint,it can be theoretically distilled into such four dimensions as the world dimension,the historical dimension,the practi...The Chinese perspective is an open and evolving theoretical system.From a spatiotemporal viewpoint,it can be theoretically distilled into such four dimensions as the world dimension,the historical dimension,the practical dimension,and the theoretical dimension,which collectively form a“unified framework of four”of logical construction.The“world”dimension represents the synchronic extension of human rights practices,outwardly touching on the shared values of all humanity guided by relational rationality and the vision of a community with a shared future for humanity.The“historical”dimension reflects the diachronic extension of China’s path of human rights development,encompassing the cultural subjectivity of Chinese civilization and the complex context of modern human rights endeavors.The“practical”dimension serves as the“meta-perspective”of contemporary Chinese perspective on human rights,where the leadership of the Communist Party of China and the people-centered approach constitute the fundamental stance for developing the perspectives of human rights and human rights governance.The“theoretical”dimension focuses on the deconstruction and reconstruction of indigenous human rights notions,emphasizing a set of values that are confident,inclusive,equitable,shared,and forward-looking.The“world”dimension of“taking the world as a method”,provides a reference perspective for“taking China as a method”narrative centered on the“historical-practical-theoretical”framework,while the latter injects a human rights methodology grounded in Chinese wisdom into the former.By integrating these four dimensions,a more profound and comprehensive understanding of the value core and normative paradigm of contemporary Chinese perspective on human rights can be achieved.展开更多
目的:针对Hefti中高等级运动项目优秀青少年运动员,进行前交叉韧带(ACL)初次损伤与膝关节解剖结构的相关性分析研究。方法:回顾性研究。连续选取2016年至2021年收治的ACL首次损伤的Hefti中高等级运动项目青少年运动员21例(研究组),男8...目的:针对Hefti中高等级运动项目优秀青少年运动员,进行前交叉韧带(ACL)初次损伤与膝关节解剖结构的相关性分析研究。方法:回顾性研究。连续选取2016年至2021年收治的ACL首次损伤的Hefti中高等级运动项目青少年运动员21例(研究组),男8例、女13例,年龄16.47±1.40岁(14~18岁),按年龄和性别1:1匹配健康青少年运动员21例(对照组)。利用磁共振测量胫骨平台后倾角(PTS)、髁间窝宽度、股骨髁形态、髁间棘高度、半月板-胫骨平台角(MBA)等指标,比较两组人群的膝关节形态差异,并分析前交叉韧带初次损伤的膝关节解剖风险因素。结果:ACL损伤的青少年运动员的外侧软组织PTS显著大于对照组(2.64°±5.59°vs-1.1°±2.64°,P<0.05),髁间窝宽度(1.61±0.19 cm vs 1.79±0.23 cm)、髁间窝宽度指数(NWI)(0.23±0.02 vs 0.25±0.02)和内侧MBA(24.9°±3.87°vs 28.1°±4.02°)小于对照组(P<0.05)。外侧软组织PTS、髁间窝宽度和内侧MBA为ACL损伤的独立风险因素。结论:外侧软组织PTS越大、髁间窝越窄、内侧MBA越小,青少年运动员ACL损伤风险越高。展开更多
Objective The alpha 2A-adrenergic receptor gene （ADRA2A） polymorphism in individuals antiplatelet response to sympathetic stimulation. The aim of this study was to investigate ADRA2A variants on platelet reactivity ...Objective The alpha 2A-adrenergic receptor gene （ADRA2A） polymorphism in individuals antiplatelet response to sympathetic stimulation. The aim of this study was to investigate ADRA2A variants on platelet reactivity in Chinese patients on dual antiplatelet therapy undergoing percutaneous coronary intervention （PCI）. modifies the the effect of （DAPT） after Methods From March 2011 to March 2013, 1,024 patients were enrolled in this prospective, single-center, observational study in China. Four single nucleotide polymorphisms （SNPs） of ADRA2A gene （rs11195419, rs3750625, rs13306146, and rs553668） and CYP2C19^＊2 were detected by ligase detection reaction （LDR）, and adenosine diphosphate （ADP） inhibition was detected by thromboelastography （TEG）. Results The minor allele frequencies of ADRA2A SNPs were common. Platelet ADP inhibition was significantly different among patients carrying rs11195419 （adjusted P = 0.022） and rs3750625 （adjusted P = 0.016）. The homozygous allele carriers had the lowest ADP inhibition. However, ADP inhibition was not significantly different in rs553668 and rs13306146. At the multivariate analysis, rs11195419 （P = 0.033）, rs3750625 （P = 0.020） and CYP2C19＂2 （P = 0.002） were independent predictors of ADP inhibition. Subgroups analysis based on sex showed rs11195419 （P = 0.003） and rs3750625 （P = 0.002） were significantly associated with ADP inhibition in males, but not in females. Conclusion ADRA2A genetic variations were associated with ADP-induced platelet aggregation during DAPT in Chinese patients undergoing PCI, and the effect was particularly more pronounced in males.展开更多
Electroencephalography(EEG)is a non-invasive measurement method for brain activity.Due to its safety,high resolution,and hypersensitivity to dynamic changes in brain neural signals,EEG has aroused much interest in sci...Electroencephalography(EEG)is a non-invasive measurement method for brain activity.Due to its safety,high resolution,and hypersensitivity to dynamic changes in brain neural signals,EEG has aroused much interest in scientific research and medical felds.This article reviews the types of EEG signals,multiple EEG signal analysis methods,and the application of relevant methods in the neuroscience feld and for diagnosing neurological diseases.First,3 types of EEG signals,including time-invariant EEG,accurate event-related EEG,and random event-related EEG,are introduced.Second,5 main directions for the methods of EEG analysis,including power spectrum analysis,time-frequency analysis,connectivity analysis,source localization methods,and machine learning methods,are described in the main section,along with diferent sub-methods and effect evaluations for solving the same problem.Finally,the application scenarios of different EEG analysis methods are emphasized,and the advantages and disadvantages of similar methods are distinguished.This article is expected to assist researchers in selecting suitable EEG analysis methods based on their research objectives,provide references for subsequent research,and summarize current issues and prospects for the future.展开更多
基金supported by the National Key R&D Program of China(Grant Nos.U25A20810 and 2024YFF0508201)the National Natural Science Foundation of China(Grant No.12302504).
文摘In coal mining on a high-pressure Ordovician limestone aquifer,grouting materials should have sufficient mechanical properties,particularly strong interfacial bonding performance to address stress concentration at the grout-limestone interface induced by rock stress disturbances during mining.In this study,graphene oxide(GO)was integrated into cement-polyacrylate composite grout to improve its interfacial bonding.First,four-point bending tests were conducted,and the Monte Carlo method combined with the simplex search algorithm was employed to determine the variations in shear cohesion and static friction parameters.The results reveal that GO can significantly increase both the tensile and shear cohesion of the grout-limestone interface,but minimally affects the interfacial friction coefficient.Second,nuclear magnetic resonance(NMR)and scanning electron microscopy(SEM)tests were performed.The results indicate that GO nanosheets result in a squamaceous microstructure of the grout consolidation mass,increasing the adhesion of the grout-limestone interface.Moreover,spiny Aft(ettringite)clusters can be induced in limestone fracture surfaces by GO,which could serve as anchors for limestone and grout consolidation mass.
基金supported by the Fundamental Research Funds for the Central Universities and Heilongjiang Provincial Natural Science Foundation of China(Grant No.YQ2020E009).
文摘Robust, ultra-flexible, and multifunctional MXene-basedelectromagnetic interference (EMI) shielding nanocomposite filmsexhibit enormous potential for applications in artificial intelligence,wireless telecommunication, and portable/wearable electronic equipment.In this work, a nacre-inspired multifunctional heterocyclic aramid(HA)/MXene@polypyrrole (PPy) (HMP) nanocomposite paper withlarge-scale, high strength, super toughness, and excellent tolerance tocomplex conditions is fabricated through the strategy of HA/MXenehydrogel template-assisted in-situ assembly of PPy. Benefiting from the"brick-and-mortar" layered structure and the strong hydrogen-bondinginteractions among MXene, HA, and PPy, the paper exhibits remarkable mechanical performances, including high tensile strength (309.7 MPa),outstanding toughness (57.6 MJ m−3), exceptional foldability, and structural stability against ultrasonication. By using the template effect ofHA/MXene to guide the assembly of conductive polymers, the synthesized paper obtains excellent electronic conductivity. More importantly,the highly continuous conductive path enables the nanocomposite paper to achieve a splendid EMI shielding effectiveness (EMI SE) of 54.1 dBat an ultra-thin thickness (25.4 μm) and a high specific EMI SE of 17,204.7 dB cm2g−1. In addition, the papers also have excellent applicationsin electromagnetic protection, electro-/photothermal de-icing, thermal therapy, and fire safety. These findings broaden the ideas for developinghigh-performance and multifunctional MXene-based films with enormous application potential in EMI shielding and thermal management.
基金supported by the Project of Sanya Yazhou Bay Science and Technology City,China(Grant No.SCKJ-JYRC-2022-94)Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDA28020203)+1 种基金Postgraduate Innovation Research Project of Hainan Province,China(Grant No.Qhyb2022-67)PhD Scientific Research and Innovation Foundation of Sanya Yazhou Bay Science and Technology City,China(Grant No.HSPHDSRF-2023-12-008).
文摘To improve the yield and quality of rice grown on saline-alkali soil,a meta-analysis combined with micro-district experimental studies was conducted in China to examine the impact of humic acidbased organic fertilizer and chemical fertilizer on rice yield and quality.This study employed a two-factor fully randomized experimental design,incorporating four levels of humic acid(F0,0.0 g/pot;F1,4.8 g/pot;F2,12.0 g/pot;and F3,19.2 g/pot)and three levels of chemical fertilizer(A1,full conventional dosage;A2,85% of conventional dosage;and A3,70% of conventional dosage).The meta-analysis revealed that the application of organic fertilizer(at a rate of 1500‒3000 kg/hm^(2))combined with chemical fertilizer had a significantly positive effect on the theoretical yield,tiller number,partial factor productivity,and SPAD value of rice.Temperature,organic fertilizer application,and chemical fertilizer levels were identified as critical factors affecting rice yield.The micro-experiments demonstrated that the application of humic acid organic fertilizer with treatment F3 significantly elevated the SPAD value at the full heading and grain filling stages.Increased panicle number and seed-setting rate were the main contributors to the rise in yield,with the F3 treatment yielding the highest overall.The effective leaf area,high-efficiency leaf area,and dry matter accumulation in rice treated with F3 were all higher compared with the F0 treatment.Our findings indicated that the addition of humic acid organic fertilizer can markedly improve the partial factor productivity and agronomic efficiency of rice.In conclusion,the application of F3 organic fertilizer combined with A3 chemical fertilizer(F3A3)significantly increased the yield of saline-alkali rice,which was 6.62% higher than that of the F0A1 treatment,thereby validating the meta-analysis outcomes.We propose that the combined use of humic acid organic fertilizer and chemical fertilizer can promote the growth of rice in saline-alkali soils.Consequently,these management practices provide a means to foster the green and healthy development of rice in saline-alkali regions across China.
基金supported by the National Natural Science Foundation of China(Grant Nos.42227804 and 42402279)the Natural Science Foundation of Shanghai(Grant No.24ZR1467500).
文摘Due to severe mass transfer limitations,the remediation efficiency of low-permeability contaminated sites often fails to meet expectations.Hydraulic fracturing technology has been utilized to enhance amendment delivery,but the influence of soil heterogeneity is commonly overlooked.To address this issue,this study develops a numerical model to simulate the enhanced transport of amendments,incorporating convection,diffusion,adsorption,and degradation processes.Within the model,random permeability fields are generated based on geostatistical methods to explore how soil heterogeneity affects amendment injection efficiency,distribution characteristics,and the underlying physical mechanisms.The results indicate that(1)soil heterogeneity significantly reduces the amendment injection efficiency,with stronger heterogeneity correlating to lower efficiency,(2)soil heterogeneity markedly alters the amendment distribution characteristics,leading to the formation of localized“nodes”,(3)the mechanism by which heterogeneity reduces injection efficiency involves decreasing the density of preferential flow paths in the soil,and(4)the adverse effects of heterogeneity can be mitigated by employing pressure compensation or adjusting well spacing.
基金This paper is a phased achievement of the Major Project of the Key Research Base for Humanities and Social Sciences of the Ministry of Education in 2024,titled“Theoretical Legal Studies in the Field of Human Rights”(Project Approval Number 24JJD820002).
文摘The Chinese perspective is an open and evolving theoretical system.From a spatiotemporal viewpoint,it can be theoretically distilled into such four dimensions as the world dimension,the historical dimension,the practical dimension,and the theoretical dimension,which collectively form a“unified framework of four”of logical construction.The“world”dimension represents the synchronic extension of human rights practices,outwardly touching on the shared values of all humanity guided by relational rationality and the vision of a community with a shared future for humanity.The“historical”dimension reflects the diachronic extension of China’s path of human rights development,encompassing the cultural subjectivity of Chinese civilization and the complex context of modern human rights endeavors.The“practical”dimension serves as the“meta-perspective”of contemporary Chinese perspective on human rights,where the leadership of the Communist Party of China and the people-centered approach constitute the fundamental stance for developing the perspectives of human rights and human rights governance.The“theoretical”dimension focuses on the deconstruction and reconstruction of indigenous human rights notions,emphasizing a set of values that are confident,inclusive,equitable,shared,and forward-looking.The“world”dimension of“taking the world as a method”,provides a reference perspective for“taking China as a method”narrative centered on the“historical-practical-theoretical”framework,while the latter injects a human rights methodology grounded in Chinese wisdom into the former.By integrating these four dimensions,a more profound and comprehensive understanding of the value core and normative paradigm of contemporary Chinese perspective on human rights can be achieved.
文摘目的:针对Hefti中高等级运动项目优秀青少年运动员,进行前交叉韧带(ACL)初次损伤与膝关节解剖结构的相关性分析研究。方法:回顾性研究。连续选取2016年至2021年收治的ACL首次损伤的Hefti中高等级运动项目青少年运动员21例(研究组),男8例、女13例,年龄16.47±1.40岁(14~18岁),按年龄和性别1:1匹配健康青少年运动员21例(对照组)。利用磁共振测量胫骨平台后倾角(PTS)、髁间窝宽度、股骨髁形态、髁间棘高度、半月板-胫骨平台角(MBA)等指标,比较两组人群的膝关节形态差异,并分析前交叉韧带初次损伤的膝关节解剖风险因素。结果:ACL损伤的青少年运动员的外侧软组织PTS显著大于对照组(2.64°±5.59°vs-1.1°±2.64°,P<0.05),髁间窝宽度(1.61±0.19 cm vs 1.79±0.23 cm)、髁间窝宽度指数(NWI)(0.23±0.02 vs 0.25±0.02)和内侧MBA(24.9°±3.87°vs 28.1°±4.02°)小于对照组(P<0.05)。外侧软组织PTS、髁间窝宽度和内侧MBA为ACL损伤的独立风险因素。结论:外侧软组织PTS越大、髁间窝越窄、内侧MBA越小,青少年运动员ACL损伤风险越高。
基金supported by grant from the National Natural Science Foundation of China[81470486]
文摘Objective The alpha 2A-adrenergic receptor gene （ADRA2A） polymorphism in individuals antiplatelet response to sympathetic stimulation. The aim of this study was to investigate ADRA2A variants on platelet reactivity in Chinese patients on dual antiplatelet therapy undergoing percutaneous coronary intervention （PCI）. modifies the the effect of （DAPT） after Methods From March 2011 to March 2013, 1,024 patients were enrolled in this prospective, single-center, observational study in China. Four single nucleotide polymorphisms （SNPs） of ADRA2A gene （rs11195419, rs3750625, rs13306146, and rs553668） and CYP2C19^＊2 were detected by ligase detection reaction （LDR）, and adenosine diphosphate （ADP） inhibition was detected by thromboelastography （TEG）. Results The minor allele frequencies of ADRA2A SNPs were common. Platelet ADP inhibition was significantly different among patients carrying rs11195419 （adjusted P = 0.022） and rs3750625 （adjusted P = 0.016）. The homozygous allele carriers had the lowest ADP inhibition. However, ADP inhibition was not significantly different in rs553668 and rs13306146. At the multivariate analysis, rs11195419 （P = 0.033）, rs3750625 （P = 0.020） and CYP2C19＂2 （P = 0.002） were independent predictors of ADP inhibition. Subgroups analysis based on sex showed rs11195419 （P = 0.003） and rs3750625 （P = 0.002） were significantly associated with ADP inhibition in males, but not in females. Conclusion ADRA2A genetic variations were associated with ADP-induced platelet aggregation during DAPT in Chinese patients undergoing PCI, and the effect was particularly more pronounced in males.
基金supported by the STI2030 Major Projects(2021ZD0204300)the National Natural Science Foundation of China(61803003,62003228).
文摘Electroencephalography(EEG)is a non-invasive measurement method for brain activity.Due to its safety,high resolution,and hypersensitivity to dynamic changes in brain neural signals,EEG has aroused much interest in scientific research and medical felds.This article reviews the types of EEG signals,multiple EEG signal analysis methods,and the application of relevant methods in the neuroscience feld and for diagnosing neurological diseases.First,3 types of EEG signals,including time-invariant EEG,accurate event-related EEG,and random event-related EEG,are introduced.Second,5 main directions for the methods of EEG analysis,including power spectrum analysis,time-frequency analysis,connectivity analysis,source localization methods,and machine learning methods,are described in the main section,along with diferent sub-methods and effect evaluations for solving the same problem.Finally,the application scenarios of different EEG analysis methods are emphasized,and the advantages and disadvantages of similar methods are distinguished.This article is expected to assist researchers in selecting suitable EEG analysis methods based on their research objectives,provide references for subsequent research,and summarize current issues and prospects for the future.
