The South-to-North Water Diversion Project in China aims to address the imbalanced distribution of water resources between the northern and southern regions,a critical safeguard for sustainable socio-economic and ecol...The South-to-North Water Diversion Project in China aims to address the imbalanced distribution of water resources between the northern and southern regions,a critical safeguard for sustainable socio-economic and ecological development.In this study,we investigated the hydroclimatic evolution of the water source area and its driving mechanisms using the inflow runoff data at Danjiangkou Reservoir from 1954 to 2013,along with multiple gridded hydroclimatic datasets.Based on the correlations between instrumental runoff data and gridded hydroclimatic variables,we used linear regression to extend the long-term runoff record to the period of 1902-2019.Our results indicate that climate changes,dominated by regional wet-dry cycles,have significant impacts on runoff variations,while the influence of human activities remains comparatively limited.Danjiangkou Reservoir can maintain a balanced base flow,even during the operation of the water diversion project.Preliminary synoptic climatology analyses reveal that runoff variations are mainly driven by the El Niño-Southern Oscillation(ENSO)and the Pacific Walker Circulation(PWC),which affect runoff by altering large-scale ocean-to-continent water vapor processes.This study advances the field by integrating multi-source data with analytical techniques,which enhances understanding of long-term runoff changes in the Danjiangkou Reservoir and their climatic drivers,ultimately supporting sustainable water resource management.展开更多
Pitch is an excellent precursor for the production of hard carbon,with pre-oxidation crucial process in the fabrication.The structural changes in the different molecular components of pitch during thermochemical treat...Pitch is an excellent precursor for the production of hard carbon,with pre-oxidation crucial process in the fabrication.The structural changes in the different molecular components of pitch during thermochemical treatment are a key factor in determining the sodium-ion storage of pitchbased hard carbon anodes.We investigated the effects of the different molecular structures in the asphaltene precursor,including aromatic rings and aliphatic chains,on the sodiumion storage behavior of the resulting carbon.We found that polar oxygen functional groups limit the steric hindrance caused by the aromatic rings in pitch,and thus facilitate the introduction of cross-linked structures.During high-temperature carbonization,aromatic rings form a rigid carbon framework that prevents the rearrangement of ordered carbon layers,leading to a short-range disordered carbon structure and promotes the production of closed pores.For example,a material prepared from asphaltene,which contains a large number of oxygen-containing functional groups and macromolecular aromatic rings,using pre-oxidation at 300℃ and carbonization at 1200℃ had a reversible capacity of 316.7 mAh g^(−1) when used as the anode for sodium ion batteries.Our research provides a theoretical basis for the selection of raw materials for the development of high-quality pitch-based hard carbons.展开更多
基金supported by the National Natural Science Foundation of China(NSFC Project No.32061123008)the Innovation Training Programme for Undergraduate Students of Yunnan University(Project No.202301051).
文摘The South-to-North Water Diversion Project in China aims to address the imbalanced distribution of water resources between the northern and southern regions,a critical safeguard for sustainable socio-economic and ecological development.In this study,we investigated the hydroclimatic evolution of the water source area and its driving mechanisms using the inflow runoff data at Danjiangkou Reservoir from 1954 to 2013,along with multiple gridded hydroclimatic datasets.Based on the correlations between instrumental runoff data and gridded hydroclimatic variables,we used linear regression to extend the long-term runoff record to the period of 1902-2019.Our results indicate that climate changes,dominated by regional wet-dry cycles,have significant impacts on runoff variations,while the influence of human activities remains comparatively limited.Danjiangkou Reservoir can maintain a balanced base flow,even during the operation of the water diversion project.Preliminary synoptic climatology analyses reveal that runoff variations are mainly driven by the El Niño-Southern Oscillation(ENSO)and the Pacific Walker Circulation(PWC),which affect runoff by altering large-scale ocean-to-continent water vapor processes.This study advances the field by integrating multi-source data with analytical techniques,which enhances understanding of long-term runoff changes in the Danjiangkou Reservoir and their climatic drivers,ultimately supporting sustainable water resource management.
文摘Pitch is an excellent precursor for the production of hard carbon,with pre-oxidation crucial process in the fabrication.The structural changes in the different molecular components of pitch during thermochemical treatment are a key factor in determining the sodium-ion storage of pitchbased hard carbon anodes.We investigated the effects of the different molecular structures in the asphaltene precursor,including aromatic rings and aliphatic chains,on the sodiumion storage behavior of the resulting carbon.We found that polar oxygen functional groups limit the steric hindrance caused by the aromatic rings in pitch,and thus facilitate the introduction of cross-linked structures.During high-temperature carbonization,aromatic rings form a rigid carbon framework that prevents the rearrangement of ordered carbon layers,leading to a short-range disordered carbon structure and promotes the production of closed pores.For example,a material prepared from asphaltene,which contains a large number of oxygen-containing functional groups and macromolecular aromatic rings,using pre-oxidation at 300℃ and carbonization at 1200℃ had a reversible capacity of 316.7 mAh g^(−1) when used as the anode for sodium ion batteries.Our research provides a theoretical basis for the selection of raw materials for the development of high-quality pitch-based hard carbons.
