A metal-organic framework/inorganic composite(ZIF-8@AMP)was synthesized by the in situ introduction of the active component ammonium phosphomolybdate(AMP)during the ambient solution-phase synthesis of the metal-organi...A metal-organic framework/inorganic composite(ZIF-8@AMP)was synthesized by the in situ introduction of the active component ammonium phosphomolybdate(AMP)during the ambient solution-phase synthesis of the metal-organic framework(ZIF-8).The structure and properties of the composite were characterized using scanning electron microscopy(SEM),X-ray powder diffraction(XRD),X-ray photoelectron spectroscopy(XPS),thermogravimetric analysis(TGA),and Fourier transform infrared spectroscopy(FTIR).Its adsorption performance for Rb^(+)and Cs^(+)in water was investigated.Results indicate that ZIF-8@AMP exhibited adsorption efficiencies of 93.5%and 95.6%for Rb^(+)and Cs^(+)within 30 min,with maximum adsorption capacities of 92.7 and 104.5 mg·g^(-1),respectively.After five adsorption-desorption cycles,it maintained high adsorption capacity and achieved over 84.9%adsorption efficiency for Rb^(+)and Cs^(+)in actual brine samples.The adsorption of ZIF-8@AMP for Rb^(+)and Cs^(+)follows pseudosecond-order kinetics and the Langmuir adsorption isotherm,indicating an endothermic,entropy-increasing,and spontaneous process.The adsorption mechanism involves electrostatic attraction and ion exchange between ZIF-8@AMP and Rb^(+)and Cs^(+).展开更多
文摘A metal-organic framework/inorganic composite(ZIF-8@AMP)was synthesized by the in situ introduction of the active component ammonium phosphomolybdate(AMP)during the ambient solution-phase synthesis of the metal-organic framework(ZIF-8).The structure and properties of the composite were characterized using scanning electron microscopy(SEM),X-ray powder diffraction(XRD),X-ray photoelectron spectroscopy(XPS),thermogravimetric analysis(TGA),and Fourier transform infrared spectroscopy(FTIR).Its adsorption performance for Rb^(+)and Cs^(+)in water was investigated.Results indicate that ZIF-8@AMP exhibited adsorption efficiencies of 93.5%and 95.6%for Rb^(+)and Cs^(+)within 30 min,with maximum adsorption capacities of 92.7 and 104.5 mg·g^(-1),respectively.After five adsorption-desorption cycles,it maintained high adsorption capacity and achieved over 84.9%adsorption efficiency for Rb^(+)and Cs^(+)in actual brine samples.The adsorption of ZIF-8@AMP for Rb^(+)and Cs^(+)follows pseudosecond-order kinetics and the Langmuir adsorption isotherm,indicating an endothermic,entropy-increasing,and spontaneous process.The adsorption mechanism involves electrostatic attraction and ion exchange between ZIF-8@AMP and Rb^(+)and Cs^(+).
