摘要
本文利用GPT方程,采取对称切割分子的方法,推导出周环反应的周边选择性规则。用此方法,可以方便地解决轮烯、多环芳烃等的周环反应的周边选择问题。
This paper introduces a derivation of the rules of periselectivity of annulenes and polynuclear aromatic hydrocarbons in pericyclic reaction from GPT equation by means of symmetrically divided molecules.This method can be con veniently used to resolve the problems in pericyclic reaction.
出处
《辽宁师范大学学报（自然科学版）》
CAS
1989年第4期38-44,共7页
Journal of Liaoning Normal University:Natural Science Edition
关键词
轮烯多环芳烃
周边选择性
周环反应
pericyclic reaction
periselectivity
GPT equation
annulenes
polynuclear aromatic hydrocarbons
electrocyclic reaction
cycloaddition reaction
