摘要
N_B_O_3-丙酮酸-H_2SO_4-[Ni(TIM)](ClO_4)_2化学振荡体系是一种新型的化学振荡体系(TIM即2,3,9,10-四甲基-1,4,8,11-四氮杂十四环-1,3,8,10-四烯)。本文用实验方法描述了该体系的振荡轨迹,为一不同于经典B-Z体系的扭曲的极限环。
Oscillating system of pyruvic acid oxidation by NaB_(?)O_3 in the presence of Nickel complex with 2, 3, 8, 9, 10-tetramethyl-1, 4, 8, 11-tetraaza-cyclotetradeca-1, 3, 8, 10- tetraene (TIM) is a new kind of B-Z system. In this paper, we have reported the experimental description of the reaction trajectory of potential of bromide- seletive electrode vs. that of plat- inum electrode for the system, which is a sprained limit cycle instead of a normal limit cycle.
出处
《安徽大学学报（自然科学版）》
CAS
1993年第2期45-48,共4页
Journal of Anhui University(Natural Science Edition)
基金
国家自然科学基金课题
关键词
振荡轨迹
化学振荡
B-Z反应
oscillating chemical reaction
macrocyclic complex
trajectory
