摘要
本文:(1)独立地用线性代数中的几何方法.较容易地证明了动力学中的一个新计量关系,k=ρ+π+ι=n+v。(2)对复杂反应的热力学平衡常数和机理中基元反应的动力学平衡常数之间的联系,提出一个新关系式。
Stoichiometric relation on species of reaction, independent reactions, sorts of atoms has been established independently. A new relation on thermodynamic and kinetic equilibrium constant is set up.
出处
《安徽大学学报（自然科学版）》
CAS
1993年第2期54-59,共6页
Journal of Anhui University(Natural Science Edition)
关键词
反应机理
计量学
热力学
kinetic mechanism
species of reaction
independent reaction
stoichiometric relation
linear transformation
thermodynamic eqilibrium constant
kinetic epuilibrium constant
