摘要
甲醇裂解以生成氢气和一氧化碳,是提高甲醇能源利用效率的一个重要途径。而选择合适的催化剂,是裂解反应的关键。综述了应用于甲醇裂解反应的非贵金属催化剂,如Cu、Ni等,包括它们的催化活性、选择性、稳定性,并对部分催化剂的制备方法、产物分析、反应动力学以及催化机理进行了概述。
Methanol decomposition to hydrogen and carbon monoxide is one of the important avenues to improve the efficiency of methanol while used as a fuel. The key problem of this reaction is to select a suitable catalyst. In this article, base metal catalysts used in the reaction, e.g. Cu, Ni, including their preparation method, product analysis, catalytic activity/selectivity, reaction dynamics and mechanism are reviewed.
出处
《化学世界》
CAS
CSCD
北大核心
2004年第6期324-328,319,共6页
Chemical World
关键词
甲醇
裂解
非贵金属
催化剂
methanol
decomposition
non-noble metal
catalysis
