期刊文献+

丙烯酸酯改性聚酯聚氨酯水分散体的合成及结构表征 被引量:1

Synthesis and Structure Characterization of Aqueous Acrylate Modified Polyurethane Dispersion
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摘要 甲基丙烯酸羟乙酯封端的水性聚氨酯预聚体与丙烯酸酯发生聚合 ,制备丙烯酸酯改性水性聚氨酯分散体。考察了工艺条件对分散体稳定性及成膜物性能的影响。同时用红外光谱和扫描电镜讨论了丙烯酸酯改性聚氨酯成膜物的结构特征 ,用热分析仪分析了膜的热稳定性能。 The title aqueous acrylate modified polyurethane dispersion has been prepared with acrylate and aqueous polyurethane prepolymer that is blocked with hydroxyethyl methacrylate.The influence of preparation technology on stability of dispersion and film performance is discussed.The film structure of the aqueous acrylate modified polyurethane is characterized by use of infrared spectrum and SEM;the thermal stability of the film is investigated by use of thermal analyzer.
出处 《涂料工业》 CAS CSCD 2004年第6期1-3,共3页 Paint & Coatings Industry
关键词 丙烯酸酯 改性技术 水性聚氨酯 合成技术 结构表征 aqueous polyurethane,acrylic acid,modification,synthesis,structure,characterization
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参考文献4

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同被引文献23

  • 1王纲,严业崧,张军,刘新泰.聚酯水分散体的合成研究[J].中国涂料,2004,19(10):20-23. 被引量:16
  • 2AWAD S,CHEN H,CHEN G,et al.Free volumes,glass transitions,and cross-links in zinc oxide/waterborne poly- urethane nanocomposites[J].Macromolecules,2011,44(1):29-38.
  • 3MELCHIORS M,SONNTAG M,KOBUSCH C,et al.Re- cent developments in aqueous two-component polyurethane (2K-PUR) coatings[J].Progress in Organic Coatings,2000,40(1-4):99-109.
  • 4CAKIC S,LACNJEVAC C,STAMENKOVIC J,et al.Effects of the acrylic polyol structure and the selectivity of the employed catalyst on the performance of two-component aqueous polyurethane coatings[J].Sensors,2007,7(3):'308-318.
  • 5魏强.双组份水性聚氨酯用聚酯水分散体的制备和改性[D].长沙:湖南大学,2010.
  • 6JACOBS P B.Two - component aqueous polyurethane dis- persions with reduced solvent content and coatings prepared therefrom with improved gloss:US,5194487[P].1993-03-16.
  • 7GE Z,LUO Y.Synthesis and characterization of siloxane- modified two-component waterborne polyurethane[J].Pro- gress in Organic Coatings,2013,76(11):1522-1526.
  • 8HUYBRECHTS J,BRUYLANTS P,VAES A,et al.Sur- factant-free emulsions for waterborne,two - component pol- yurethane coatings[J].Progress in Organic Coatings,2000,38(2):67-77.
  • 9KONG X,LI S,QU J,et al.Self-emulsifying hydroxy a- crylic polymer dispersions for two component waterborne polyurethane coatings[J].Journal of Macromolecular Sci- ence,Part A:Pure and Applied Chemistry,2010,47(4),368-374.
  • 10LEY D A,FIORI D E,QUINN R J.Optimization of acrylic polyols for low VOC two-component water reducible polyu- rethane coatings using tertiary isocyanate crosslinkers[J].Progress in Organic Coatings,1999,35(1-4):109-116.

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