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聚四氨基酞菁钴对氧还原的电催化性质

THE ELECTROCATALYTIC REDUCTION OF DIOXYGEN ON A GLASS CARBON ELECTRODE MODIFIED WITH POLY COBALT TETRRAAMINOPHTHALOCYANINE FILM
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摘要 研究了聚四氨基酞菁钴修饰电极(p-CoTAPc/GC)催化氧还原反应的性质。用电聚合法在玻碳电极上制备p-CoTAPc/GC,并用循环伏安法研究其对氧还原催化的性质。结果表明:氧气的浓度及扫速对催化存在影响,随着氧气浓度的增加催化反应速度加快。 Objective: To investigate the electrocatalytic reduction of dioxygen on a glass carbon electrode modified with poly cobalt tetrraaminophthalocyanine film (p - CoTAPc/GC) . Method: p - CoTAPc/GC was prepared by electropolymerization, and the electrocatalytic reduction of dioxygen on p - CoTAPc/GC was studied using cyclic voltammetry. Result indicated: Concentration of dixygen and scan rates affect on electrocataly for dioxygen. Conclusion : The rate of catalytic react increases with increase of concentration of dioxygen
出处 《佳木斯大学学报(自然科学版)》 CAS 2004年第1期84-86,共3页 Journal of Jiamusi University:Natural Science Edition
关键词 电催化 聚四氨基酞菁钴 修饰电极 电聚合法 cobalt tetrraaminophthalocyanine electro - catalytic dioxygen
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参考文献4

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  • 3Mandakini Kanungo, Anil Kumar, A.Q. Contractor, studies on electropolymerization of aniline in the presence of sodium dodecyl sulfate and its application in sensing urea [J]. Electroanal. Chem. 2002, 5 (28): 46-56.
  • 4B. N. Achar, G. M. Fohlen, J. Keshavayya, Synthesis and structural studies of metal (Ⅱ) 4,9,16,23-phthalocyanine tetraamines [J]. Polyhedron, 1987, 6 (4): 1463 - 1463.

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