锰钨硫原子簇合物的合成

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摘要 Müller,在1981年和1986年两次对钼、钨、硫原子簇合物做了系统总结,认为MS_4^(2-)(M=Mo、W)可作为双齿配体与过渡金属配位,形成多种类型的杂核原子簇合物。已经报道的配位过渡金属有Fe(Ⅱ,Ⅲ)、Co(Ⅱ,Ⅲ)、Ag(Ⅰ)、Cu(Ⅱ),Au(Ⅰ)、Ni(Ⅱ)、Cu(Ⅱ)、Zn(Ⅱ)、Cd(Ⅱ)、Pd(Ⅱ)和Pt(Ⅱ)。最近又报道了含Ru(Ⅲ)、Rh(Ⅲ)的簇合物。

作者王文忠忻新泉戴安邦金通政

机构地区南京大学配位化学研究所南京大学现代分析中心

出处《科学通报》 EI CAS CSCD 北大核心 1989年第21期1636-1638,共3页 Chinese Science Bulletin

基金国家自然科学基联合国教科文组织资助

关键词锰钨硫原子簇合物杂核

分类号 O641.4 [理学—物理化学]

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1金国新，南京大学学报，1987年，23卷，4期，718页

1WU Bao-Shan ,SUO Quan-Ling,WU Ren,LU Qing-Wei,WANG Yi-Bing(Department of Chemical Engineering, Inner Mongolia Polytechnic University,Hohhot, 010062)CHEN Jiu-Tong,HUANG Xiao-Ying(Fujian Institute of Research on the Structure of Matter,the Chinese Academ.Crystal Structure of 〔(Ph_3P)_2N〕〔FeCo_3(CO)_(12)〕[J].Chinese Journal of Structural Chemistry,1998,17(2):101-104.
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1989年第21期

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锰钨硫原子簇合物的合成

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