摘要
采用水热合成和恒温加热合成方法,得到了两种Ln3+的配合物[Nd(oxinate)(phen)2(NO3)2]·(CH3OH)1/2(1)和Sm(phen)2(CH3COO)3(2).对这两种化合物的单晶进行了X-射线衍射分析,确定了它们的结构.并对这两种化合物的UV VIS NIR,IR和荧光光谱进行了测定和分析.
Two Ln^(3+) complexes, ·_(1/2)(1) and Sm(phen)_2(CH_3COO)_3(2), have been synthesized. Both the single crystals of complexes were determined by X-ray diffraction. Also, the UV-VIS-NIR ,IR and fluorescence spectra of the two complexes were measured and analyzed.
出处
《辽宁师范大学学报(自然科学版)》
CAS
2004年第1期45-49,共5页
Journal of Liaoning Normal University:Natural Science Edition
基金
国家自然科学基金资助项目(90201018)