摘要
综述了金属酞菁轴向配合物的合成方法 ,结构表征及其物理化学性质。金属酞菁轴向配合物的合成重点在于单体的合成。轴向配合物的合成通常有两种方法 :一种是通过金属酞菁的单体来直接合成 ,这种方法分别可以通过三条途径来达到 ,一是以苯腈为原料的途径 ,二是以苯酐为原料的途径 ,三是二亚氨基异吲哚啉路线 ,它们都是以单体为原料 ;第二种合成方法是通过金属酞菁聚合物在配体溶剂中的解离而得到的。金属酞菁轴向配合物的吸收光谱与简单的金属酞菁配合物相比 ,吸收峰明显红移 。
In this paper,the different methods of synthesising phthalocyaninatometal ,its s tructure characterization and chemical and physical properties were reviewed.Th e synthesizing methods of phthalocyaninatometal which emphases on the synthesis of monomers usually include two routes : phthalocyaninatometal synthesized is wi th the monomers directly,this way can be completed with three routes:benzd nitri le method,benzoic anhydride method and diiminoisoindoline method;the other is th rough decomposition of the poly phthalocyaninatometal in the organic solvent .Th e absorption spectrum of the complex is bathochromic shifted and sharpened in co mpared with that of monomer phthalocyanine as a result the optical properties of the dye films is improved.
出处
《化工新型材料》
CAS
CSCD
2004年第2期25-28,共4页
New Chemical Materials
基金
教育部<高等学校骨干教师资助计划项目>资助
