摘要
A study of the core-electron x-ray photoelectron spectra showed the presence of satellite structure for the 3d and 4d signals in Ce_2O_3, CeO_2, CeCl_3, CeF_3. These satellites are discussed in terms of coexcitation of the charge transfer type principally O2p to Ce4f transitions. It is confirmed that in the cerium compounds studied the satellites are due to energy-loss (representing shake-up) rather than energy-gain (shake-down) processes.
A study of the core-electron x-ray photoelectron spectra showed the presence of satellite structure for the 3d and 4d signals in Ce_2O_3, CeO_2, CeCl_3, CeF_3. These satellites are discussed in terms of coexcitation of the charge transfer type principally O2p to Ce4f transitions. It is confirmed that in the cerium compounds studied the satellites are due to energy-loss (representing shake-up) rather than energy-gain (shake-down) processes.
出处
《应用化学》
CAS
CSCD
北大核心
1992年第1期65-68,共4页
Chinese Journal of Applied Chemistry
基金
国家自然科学基金
关键词
铈
价态
伴峰结构
XPS
cerium, x-ray photoelectron spectrascopy, satellite structure, valence state
