摘要
β 氟砜基全氟醚基取代四芳基卟啉与 5 (4 羟苯基 ) 10 ,15 ,2 0 三苯基卟啉、BINOL反应分别生成meso ,β 和 β ,β 全氟醚基磺酸酯桥连双卟啉 ,双卟啉与醋酸锌在CHCl3 /CH3 OH中回流可高产率获得双锌卟啉 ,测定并讨论了meso ,β 和 β ,β
Fluorosulfonylperfluoroetheryltetraaryl porphyrins reacted with 5-(4-hydroxyphenyl)- 10,15,20-tri^phenylporphyrin and BINOL to afford meso,β- or β,β-perfluoroetherylsulfonyl ester linked diporphyrins. Treatment of the diporphyrins with zinc acetate in CHCl 3/CH 3OH under refluxing for 1 h gave diporphinatozinc. UV-vis absorption and fluorescence data of meso,β- and β,β-diporphyrins were determined and discussed.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
2004年第3期288-294,共7页
Acta Chimica Sinica
基金
国家自然科学基金 (Nos.2 9972 0 51
D2 0 0 32 0 1 0 )资助项目
