摘要
研究了四 (对氯苯基 )卟啉及其羟基稀土配合物的紫外 -可见光谱、红外光谱和拉曼光谱 ,对主要谱带进行了经验归属 ,讨论了中心离子对紫外光谱和共振拉曼光谱结构敏感带频率的影响 .
The UV-Vis spectra, Infrared spectra and resonance Raman spectra of tetra(para-chlorophenyl)porphyrin and its coordination compounds LnT(%p%-Cl)PPOH(Ln: Tb, Lu, Er, Gd) were measured and investigated respectively. In UV-Vis spectra the effect of rare earth ions were discussed. Metal sensitive bands in IR spectra were found, and the effect of metal ion size on the marker bands frequencies in resonance Raman spectra was also discussed.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2004年第2期338-341,共4页
Chemical Journal of Chinese Universities
基金
国家自然科学基金 (批准号 :2 0 173 0 19
2 0 2 73 0 2 2
2 9975 0 11)资助
