摘要
将二茂铁甲酰丙酮与水杨酰肼缩合,得含二茂铁基的多齿配体C_5H_5FeC_5H_4C(OH)=CHC(CH_3)=NNHCOC_6H_4OH(简记作FcacacshH_2),该配体分别与d-过渡、ⅡB族及主族金属乙酸盐反应,合成了几个中性固体配合物。经元素分析、红外光谱、紫外—可见光谱、氢核磁共振谱、穆斯堡尔谱、摩尔电导测定对配合物进行表征并研究其性质。
A new quatedentate ligand C5H5FeC5H4C(OH) = CHC(CH3) = NNHCOC6H4OH (FcacacshH2) was prepared by the condensation of ferrocenoylacetone and salicyloylhydrazine in methanol and its d-transition, H B group and main group metal complexes (FcacacshHx)yM(M = T1, x=1, y=1; M = Pb, Cd, Ni, x = 0, y=1; M = Zn, Mn, Co, x=1, y=2) were synthesized via the reaction of FcacacshH2 with relevant metal acetate. The IR, UV-Vis, 1HNMR, 57Fe Mossbauer spectra and molar conductance of the ligand and the complexes were studied.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1992年第2期130-134,共5页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金
关键词
二茂铁
四齿配体
金属配合物
ferrocene quatedentate ligand metal complex
