摘要
Dissymmetry model of molecular polarizability divided into some layers within a sphere,some rules and sequence according to the magnitude of polarizability replaced by bond refraction for many groups have been suggested.The relationship between the dissymmetry of molecular polarizability arrounding the dissymmetric carbon atom and the direction of optical activity has been discussed .The accuracy is above 95 persent to use our model and rules to determine over 6000 compounds of optical activity.
<正> Dissymmetry model of molecular polarizability divi-ded into some layers within a sphere, some rules and sequence acco-rding to the magnitude of polarizability replaced by bond refractionfor many groups have been suggested. The relationship between thedissymmetry of molecular polarizabi li tY arrounding the dissymmetr-ic carbon atom and the direction of optical activity has been disc-ussed. The accuracy is above 95 persent to use our model and rulesto determine over 6000 compounds of optical activi t^d.
出处
《苏州大学学报（自然科学版）》
CAS
1991年第2期197-208,共12页
Journal of Soochow University(Natural Science Edition)
关键词
非对称模型
分子极化度
光学活性
碳原子
Optical Activity, Model with Multilayers of Polarizability Sphere, Bond Refraction, Sequence in Refraction Magnitude for Substituents.
