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反式氯氰菊酯对映异构体的分离 被引量：1

The Resolution of theta-Cypermethrin Enantiomers
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摘要 Cellulose-tris(3,5-dimethylphenylcarbamate)(CDMPC) was used as a chiral stationary phase for resolution of theta-cypermethrin racemate by HPLC with n -hexane-isopropanol as mobile phase. The influences of isopropanol concentration in the mobile phase, temperature and the column length on the resolution were investigated. The resolution capacity was increased with decrease of isopropanol fraction in the mobile phase and the column temperature. The results revealed good chiralselectivity to theta-cypermethrin by HPLC using CDMPC as stationary phase. Cellulose-tris(3,5-dimethylphenylcarbamate)(CDMPC) was used as a chiral stationary phase for resolution of theta-cypermethrin racemate by HPLC with n -hexane-isopropanol as mobile phase. The influences of isopropanol concentration in the mobile phase, temperature and the column length on the resolution were investigated. The resolution capacity was increased with decrease of isopropanol fraction in the mobile phase and the column temperature. The results revealed good chiralselectivity to theta-cypermethrin by HPLC using CDMPC as stationary phase.
作者 王鹏 江树人 周志强
机构地区 中国农业大学理学院应用化学系
出处 《应用化学》 CAS CSCD 北大核心 2004年第1期96-97,共2页 Chinese Journal of Applied Chemistry
关键词 反式氯氰菊酯 拆分 手性固定相 theta-cypermethrin,chiral separation,cellulose-tris-dimethylphenylcarbamate
分类号 O658 [理学—分析化学]
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参考文献2

  • 1侯世聪 王敏 周志强.Pesticides(农药)[J],2001,40(12):7-7.
  • 2周志强 王鹏 江树人.Chin J Chromatogr(色谱)[J],2003,21(1):44-44.

同被引文献37

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应用化学
2004年 第1期

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