摘要
Nanometer perovskite LaMnO 3+λ, La 0.6Ce 0.4MnO 3+λ and La 0.6Sr 0.4MnO 3+λ were prepared by citric acid-aid ed sol-gel method. The effects of Ce, Sr on the structure and properties of nan ometer perovskite were studied through DT-TGA, XRD, TEM and BET analyses. The r esults show that, by sol-gel method, LaMnO 3+λ, La 0.6Ce 0. 4MnO 3+λ and La 0.6Sr 0.4MnO 3+λ were made with average particle size of about 60, 100 and 30 nm, respectively. After partially substituting Sr on La positions in LaMnO 3+λ, it is found that Sr is l ocated at the perovskite lattice so as to reduce the formation temperature of th e perovskite. As a result, the perovskite has a smaller particle size and larger specific surface area. On the contrary, it is difficult for Ce to enter the per ovskite lattice. Ce exists mostly in the form of CeO 2 as partially substitutin g La in LaMnO 3+λ. The formation temperature of the perovskite increas es, and the catalyst containing CeO 2 presents a larger particle size and less specific surface area.
Nanometer perovskite LaMnO 3+λ, La 0.6Ce 0.4MnO 3+λ and La 0.6Sr 0.4MnO 3+λ were prepared by citric acid-aid ed sol-gel method. The effects of Ce, Sr on the structure and properties of nan ometer perovskite were studied through DT-TGA, XRD, TEM and BET analyses. The r esults show that, by sol-gel method, LaMnO 3+λ, La 0.6Ce 0. 4MnO 3+λ and La 0.6Sr 0.4MnO 3+λ were made with average particle size of about 60, 100 and 30 nm, respectively. After partially substituting Sr on La positions in LaMnO 3+λ, it is found that Sr is l ocated at the perovskite lattice so as to reduce the formation temperature of th e perovskite. As a result, the perovskite has a smaller particle size and larger specific surface area. On the contrary, it is difficult for Ce to enter the per ovskite lattice. Ce exists mostly in the form of CeO 2 as partially substitutin g La in LaMnO 3+λ. The formation temperature of the perovskite increas es, and the catalyst containing CeO 2 presents a larger particle size and less specific surface area.
基金
ProjectsupportedbyAcademicTeacherSustentationFundofMinistryofEducationofChina ( 2 0 0 0~ 2 0 0 1)
