摘要
Photo-catalytic TiO 2 was prepared from tetraisopropyl titanate (TPT) in supercritical ethanol. It was found that TPT in supercritical ethanol could be effectively converted into the anatase-form of TiO 2 crystallites. The anatase-form of TiO 2 as a photo-catalyst was evaluated for its adsorptivity and subsequent photo-catalytic activities on formaldehyde, one of the harmful air pollutants in the environment. As a result, the supercritically treated TiO 2 had a high decomposing ability. Under the same condition, the experiment was repeated for 5 times,and photocatalysis of the samples did not decrease. This indicated that the supercritical treatment was effective to prepare photo-catalytic TiO 2, which was feature by stability, longevity and high photo-catalytic decomposition of formaldehyde for environmental cleaning. Meanwhile, unlike conventional chemical reaction, which is complex and time-consuming, supercritical treatment is easy to operate, saving both time and labor.
Photo-catalytic TiO 2 was prepared from tetraisopropyl titanate (TPT) in supercritical ethanol. It was found that TPT in supercritical ethanol could be effectively converted into the anatase-form of TiO 2 crystallites. The anatase-form of TiO 2 as a photo-catalyst was evaluated for its adsorptivity and subsequent photo-catalytic activities on formaldehyde, one of the harmful air pollutants in the environment. As a result, the supercritically treated TiO 2 had a high decomposing ability. Under the same condition, the experiment was repeated for 5 times,and photocatalysis of the samples did not decrease. This indicated that the supercritical treatment was effective to prepare photo-catalytic TiO 2, which was feature by stability, longevity and high photo-catalytic decomposition of formaldehyde for environmental cleaning. Meanwhile, unlike conventional chemical reaction, which is complex and time-consuming, supercritical treatment is easy to operate, saving both time and labor.
出处
《化工学报》
EI
CAS
CSCD
北大核心
2003年第9期1315-1318,共4页
CIESC Journal
基金
国家留学基金资助项目~~
关键词
甲醛
超临界乙醇
TIO2
光催化活性
formaldehyde, supercritical ethanol, TiO 2, photo-catalytic activity
