摘要
提出了计算速率常数的精细态—态过渡态表达式,考虑隧道效应的计算结果与实验结果符合得较好,特别是室温以下,未考虑隧道效应的计算值偏离,实验结果较明显。
A detailed state-to-state TST expression for the rate constant was sugg-ested.The results calculated by using tunneling reaction probabilities are goodagreement with experimental values,especially below room temperature,the diff-erence between the calculated results without tunneling and experimental valuesis obvious.
出处
《山东大学学报（自然科学版）》
CSCD
1992年第2期242-246,共5页
Journal of Shandong University(Natural Science Edition)
基金
山东大学青年基金
