摘要
目前, 铅钙锡合金已广泛用作阀控式铅酸蓄电池(VRLAB)的板栅材料[1].由于钙的存在, 使铅钙锡合金阳极氧化时易形成高阻抗的阳极腐蚀层, 并出现晶间腐蚀, 电池循环充放电能力仍不理想[2].
The anodic behavio of Pb-(0. 075%-0. 73%)Sm-0. 63%Sn and Pb-0. 088%Ca-0. 63%Sn alloys in sulfuric acid solution has been studied by using cyclic voltammetry, linear sweep voltammetry and impedance-time curves. The experimental results show that samarium in the Pb-Sm-Sn alloy can inhibit the growth of the anodic corrosion layer(PbO2) formed on the alloy. Moreover, the evolution of oxygen at the Pb-Sm-Sn alloy electrode is less than that at the Pb-Ca-Sn alloy electrode. 2 V-200 A·h VRLA batteries were manufactured by using the above two alloy positive grids separately. The corrosion layers formed on the positive gird surfaces after the life test of the batteries were observed by SEM. The results of the test show that the capacity loss of the battery with the Pb-Sm-Sn positive grids is significantly less than that of the battery with the Pb-Ca-Sn positive grids, and the longer floating charge life of the battery with the Pb-Sm-Sn positive grids is caused by the better corrosion-resistant performance of the Pb-Sm-Sn alloy with the anodic corrosion layer having a finer grain structure.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2003年第9期1677-1679,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金(批准号:20173013
29873013)
