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一种新型非贵金属氧还原电催化剂 被引量:4

A new non-noble metal electro-catalyst for the reduction of oxygen
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摘要 用N4-金属大环化合物作为非贵金属氧还原电催化剂是一个很有希望的途径。综述了N4-金属大环化合物的阴极氧还原电催化性质 ,讨论了中心金属原子、热处理大环化合物对催化剂性能的影响 ,介绍了这类催化剂的制备方法及其抗甲醇性能 ,并指出了这类催化剂存在的问题及其发展方向。 N4- metal macro-cyclic compound was a hopeful electro-catalyst oxygen reduc tion.The electro-catalyst properties of the compound for oxygen reduction were reviewed.The influence of the central metal atom,heat treatment of N4- metal macro-cyclic compound on the catalytic performance was discussed.The preparati on methods and methanol tolerant properties of the compound were introduced,the problems and the prospects of the catalyst were suggested.
出处 《电池》 CAS CSCD 北大核心 2003年第4期245-248,共4页 Battery Bimonthly
关键词 聚合物电解质燃料电池 阴极 电催化剂 非贵金属 氧还原 N_4-metal macro-cyclic compound cathode oxygen reduction electrocatalyst s
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参考文献22

  • 1童叶翔,刘鹏,沈培康,杨绮琴.质子交换膜和直接甲醇燃料电池进展[J].电池,2002,32(3):178-180. 被引量:13
  • 2Wiesener K, Ohms D, Neumann V,et al. N4 - mscrocycles as electrocatalysts for the cathodic reduction of oxygen[ J ]. Materials Chemistry and Physics, 1989, 22(3 - 4) :457 - 475.
  • 3Reeve R W, Christensen P A, Dickinson A J, et at. Methanol-tolerant oxygen reduction catalysts based on transition metal sulfides and their application to the study of methanol permeation[J]. Electrochimica Acta, 2000, 45 : 4 237 - 4 250.
  • 4Gouereca P, Savya M, Riga J. Oxygen reduction in acidic media catalyzed by pyrolyzed cobalt macrocycles dispersed on an active carbon:The importance of the content of oxygen surface groups on the evolution of the chelate structure during the heat treatment[J]. Electrochimica Acta, 1998, 43(7) :743 - 753.
  • 5Beck F. The redox mechanism of the chelate-catalysed oxygen cathode[ J ]. J Appl Eleetrochem, 1977, 7 : 239 - 245.
  • 6Gupta S, Tryk D, Zecevic S K,et al. Methanol-tolerant electrocatalysts for oxygen reduction in a polymer electrolyte merabrane fuel cell[J].J Appl Electrochem, 1998, 28:673 - 682.
  • 7Coutanceau C, Ei H A, Crouigneau P, a al. Conducting polymer electrodes modified by metal tetrasulfonated phthalocyanines;preparation and electrocatalytic behaviour towards dioxygen reduction in acid medium[ J ]. Electrochimica Acta, 1995, 40 ( 17 ) : 2 739 -2 748.
  • 8Deryn C, Rongzhong J. Novel electrocatalysts for direct methanol fuel cells[J]. Solid State Ionics, 2002, 148 : 591 - 599.
  • 9Sun G Q, Wang T, Gupta S, et al. Iron ( Ⅲ ) tetramethoxy phenyl porphyrin(FeTMPP-Cl) as ehctrocatalyst for oxygen reduction in direct methanol fuel cells[J] .J Appl Electrochem, 2001, 31(9) : 1 025- 1 031.
  • 10Ladouceur M,Lalande G,Guay D,et al.Pyrolyzed cobalt phthalocyanine as electrocatalyst for oxygen reution[J].J Electrochem Soc,1993,140:1974-1981

二级参考文献7

  • 1李文震 梁长海 等.多壁碳纳米管作为直接甲醇燃料电池阴极催化剂载体的研究.第11届全国电化学会议论文[M].南京,2001.B077.
  • 2杨春晓 石瑶 等.质子交换膜燃料电池纳米铂催化剂研究.第11届全国电化学会议论文[M].南京,2001.B087.
  • 3李忠芳 张军 等.直接甲醇燃料电池研究进展及关键技术评述.第十一次全国电化学会议论文集[M].南京,2001.B074.
  • 4邢巍 李长志 等.直接甲醇燃料电池的研究进展.第11届全国电化学会议论文[M].南京,2001.B072.
  • 5李磊 王宇新.直接甲醇燃料电池新型聚合物膜的研究.第11届全国电化学会议论文[M].南京,2001.B076.
  • 6史萌,邱新平,朱文涛.Nafion膜在直接甲醇燃料电池中的应用及改进[J].化学通报,2001,64(8):488-491. 被引量:12
  • 7侯明,吴金锋,衣宝廉,韩明.PEM燃料电池流场板[J].电源技术,2001,25(4):294-298. 被引量:24

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