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Measurement of surface crystallinity of PAA and PAANa coatings and its effect on hydrophilicity of coatings

Measurement of surface crystallinity of PAA and PAANa coatings and its effect on hydrophilicity of coatings
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摘要 The solutions of poly(acrylic acid)(PAA), poly(acrylic acid sodium)(PAANa) were coated on aluminium fins by roll coating method. The coatings with different crystallinity were obtained by varying baking time and temperature. Their surface crystallinity and surface tension were measured, and their spreading speed constant and equilibrium contact angle were tested also. The correlation of surface crystallinity, surface tension, spreading speed constant and surface hydrophilicity was discussed. It is demonstrated that surface tension and spreading speed constant increase, while equilibrium contact angle declines with increasing surface crystallinity of coatings, that is to say, the hydrophilicity of coatings is improved with surface crystallinity of coatings increasing. The solutions of poly(acrylic acid)(PAA), poly(acrylic acid sodium)(PAANa) were coated on aluminium fins by roll coating method. The coatings with different crystallinity were obtained by varying baking time and temperature. Their surface crystallinity and surface tension were measured, and their spreading speed constant and equilibrium contact angle were tested also. The correlation of surface crystallinity, surface tension, spreading speed constant and surface hydrophilicity was discussed. It is demonstrated that surface tension and spreading speed constant increase, while equilibrium contact angle declines with increasing surface crystallinity of coatings, that is to say, the hydrophilicity of coatings is improved with surface crystallinity of coatings increasing.
出处 《中国有色金属学会会刊:英文版》 CSCD 2003年第4期988-993,共6页 Transactions of Nonferrous Metals Society of China
关键词 PAA PAANa 结晶度 测量 亲水性 涂层 PAA PAANa surface crystallinity surface tension hydrophilicity spreading speed constant
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  • 1卜海山,高分子学报,1985年,3期,191页
  • 2于同隐,高分子学报,1981年,6期,461页

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