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煤燃烧过程中汞、砷、硒反应机理研究 被引量:9

THE BEHAVIOUR OF MERCURY, ARSENIC,SELENIUM DURING COAL COMBUSTION
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摘要 本文以三种典型煤为对象,测定了煤及灰中汞,砷,硒的浓度,了解了元素的挥发性.对钱家营褐煤进行了不同温度的燃烧实验.测定了在不同温度下燃烧灰中汞,砷,硒的含量变化.将所得实验结果与化学热力平衡分析工具F*A*C*T2.1模拟系统结果相比较.推测了其中可能发生的反应. The concentration of mercury, arsenic and selenium in three typical coals and high temperature ash were determined. The behaviour of three elements during coal combustion were also investigated in different temperature. We also compare the result with that of chemical thermodynamic equilibrium calculation. According to above experiment data we suggest some potential mechanism involved.
出处 《工程热物理学报》 EI CAS CSCD 北大核心 2003年第4期703-706,共4页 Journal of Engineering Thermophysics
基金 国家自然科学基金(No.59876013) 国家重点基础研究专项经费资助(No.G199902212)
关键词 温度 蒸发率 coal mercury arsenic selenium temperature vapor rate
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参考文献7

  • 1郭欣,郑楚光,刘迎晖,刘晶,陆晓华.煤中汞,砷,硒赋存形态的研究[J].工程热物理学报,2001,22(6):763-766. 被引量:45
  • 2Joseph J Helble, Wahab Mojtahedi, Jussi Lyyranen.Jorma Jokiniemi and Esko Kauppinen. Trace Element Partitioning During Coal Gasification. Fuel, 1996, 75(8):931-939.
  • 3Xavier Querol, Roberto Juan, Angel Lope-Soler, et al.Mobility of Trace Elements from Coal and Combustion Wastes. Fuel, 1996, 75:821-838.
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  • 7Anders W Andren, David H Klein, Selenium in Coal Fired Steam Plant Emissions. Environmental Science & Technology, 1975, 9(9): 856-858.

二级参考文献4

  • 1[1]Finkelman R B. Mode of Occurrence of Potentially Hazardous Elements in Coal: Levels of Confidence. Fuel Proc. Technol., 1994, 39:21-34
  • 2[2]Swaine D J. Trace Elements in Coal and Their Dispersal during Combustion. Fuel Process. Technol., 1994, 39:121-137
  • 3[3]Querol X, Fernandez-Turiel J L, Lopez-Soler A. Trace Element in Coal and Their Behaviour during Coal Combustion in a Large Station. Fuel, 1995, 74(3): 331-343
  • 4[4]Xavier Querol, Roberto Juan, Angel Lope-Soler, et al. Mobility of Trace Elements from Coal and Combustion Wastes. Fuel, 1996, 75:821-838

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