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正己烷在几种改性分子筛上的氢转移反应 被引量:1

HYDROGEN TRANSFER REACTION OF n-HEXANE OVER SEVERAL TYPES OF MODIFIED ZEOLITES
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摘要 以正己烷为模型化合物 ,在接近工业催化裂化 (FCC)过程的反应温度下 ,考察了几种改性分子筛在催化裂化过程中的氢转移反应性能。结果表明 ,分子筛中引入适量的磷、硼以及经过酸改性 ,可以有效地提高选择性氢转移反应而抑制非选择性氢转移反应。 Using n-hexane as a model compound,hydrogen transfer reaction activity over several types of modified zeolites under FCC processing conditions are investigated. The results show that zeolites modified properly by phosphorus,boron and acid treatment can effectively enhance selective hydrogen transfer reaction and cracking conversion,while inhibit non-selective hydrogen transfer reaction.
出处 《石油与天然气化工》 CAS CSCD 北大核心 2003年第3期121-123,共3页 Chemical engineering of oil & gas
关键词 正己烷 改性分子筛 氢转移反应 催化裂化 孔结构 酸性 石油炼制 汽油 zeolite, hydrogen transfer reaction, FCC, pore structure, acidity
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参考文献6

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同被引文献9

  • 1Baba T,Abe Y.Metal cationacidic proton bifunctional catalyst formethane activation:Conversion of 13CH4 in the presence of ethyleneover metal cations-loaded H-ZSM-5. Appl.Cata.A:Gen . 2003
  • 2Fang L,Yongdan L.A FTIR and TPD examination of the distributiveproperties of acid sites on ZSM-5 zeolite with pyridine as a probemolecule. Catalysis Today . 2008
  • 3Haag W O,Lago R M,Rodewald P G.Aromatics,Light olefinand Gasoline from methanol:mechanistic pathway with ZSM-5zeolite catalyst. Journal of Molecular Catalysis . 1982
  • 4Michael Stocker.Methanol-to-hydrocarbons: catalytic materials and their behavior. Microporous and Mesoporous Materials . 1999
  • 5H.A. Zaidi,K.K. Pant.Catalytic conversion of methanol to gasoline range hydrocarbons. Catalysis Today . 2004
  • 6Ono Y,,Adachi H.Selective conversion of methanol into aromatic hydro-carbonover Zinc-exchanged ZSM-5 zeolites. J Chem Soc FaradayTrans . 1988
  • 7Freeman D,Wells RP K,Hutchings GJ.Conversion of methanol to hy-drocarbons over Ga2O3/H-ZSM-5 and Ga2O3/WO3catalysts. Journal of Catalysis . 2005
  • 8田涛,骞伟中,孙玉建,崔宇,卢俨俨,魏飞.Ag/ZSM-5催化剂上甲醇芳构化过程[J].现代化工,2009,29(1):55-58. 被引量:44
  • 9尹双凤,陈懿,林洁,于中伟.正己烷在Zn/HZSM-5上芳构化反应机理的探讨[J].工业催化,2002,10(1):33-37. 被引量:28

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