摘要
同种类型金属硫化物溶解度的大小主要取决于离子极化作用和阳离子水合焓,在某些硫化物中可能离子极化作用或阳离子水合焓单方面起决定作用,而另一些硫化物中这两种因素均不可忽视。
Thermodynamic factors influencing solubility of insoluble sulfides with dx cations were studied considering ionic polarization energy, hydration enthalpy, entropy effect and so on. Solubility of the congeneric sulfide is determined by polarization effect and hydration enthalpy of the cation primarily, one of them is the only decisive factor in some sulfides, and both of them are important in others.
出处
《安庆师范学院学报（自然科学版）》
2003年第2期21-22,共2页
Journal of Anqing Teachers College(Natural Science Edition)
关键词
d^x结构
金属硫化物
溶解度
离子极化能
热力学
d^x structure
metallic sulfide
solubility
ionic polarization energy
thermodynamics
