摘要
过渡元素的无机桥配体桥联化合物按所含桥配体的原子种类可分为含氧、卤素、氢、双氧、磷和硫等原子的桥配体桥联化合物。桥联的出现使化合物表现出花样繁多的价键本性及空间结构,既促进了化学健理论的发展,也促进了配位催化及生物模拟的发展。因此,本文对无机配体桥联化合物的结构、功能及生物活性进行了讨论。
The coordination - bridged compounds inorganic bridging ligands of transition metals are classified into containing oxygen, halogens, hydrogen, double oxygen, phosphorus and sulphur - bridging ligand compounds. Bridging ligands involved in compounds reveals the various valence - bond nature and steric structrue, which promote the development of valence - bond theory, coordination catalyst as well as biology simulation. The structure, function and synthesis of those are discussed .
出处
《化工时刊》
CAS
2003年第3期1-4,共4页
Chemical Industry Times
基金
陕西省自然科学资金项目(2001H19)
陕西省教育厅专项科研资金资助项目(01JK0T0)
