摘要
The paper presents an analysis of characteristic karst tufa from Guangxi, China, which has not been studied before. A comparison with tufa from Dinaric Karst of Croatia is discussed in view of the C-type climate. The major mineral is calcite. Minor minerals are quartz and dolomite, depending on location. The content of calcium carbonate varies from 65% to 92%, and that of magnesium carbonate from 0.03% to 1.77%. Among other elements, the most abundant are Fe, from 0.02% to 1.50%, and Ti, from 0.15% to 0.27%. Many other trace elements (V, Cr, Mn, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Y, Zr, Hg and Pb) are also present. Specific activity of radionuclides 40K, 232Th, 137Cs, 226Ra and 238U varies from sample to sample. Concentration of U in tufa is close to that reported for sedimentary carbonate. Low concentration of 137Cs indicates that this part of the world was not exposed to nuclear explosions. The concentration of 226Ra is the highest in Mashan County. The ratio 238U/226Ra (0.21-0.71) in tufa from Mashan County is significantly lower than the theoretical value of 1. In 5 of the 11 studied samples, stable isotopes δ13C and δ18O were analyzed. They were dated by means of the 14C method. One tufa sample originated in the Pleistocene and the others in the Holocene. Because all of the tufa samples contain traces of Na and K, and K < Na, the tufa from Guangxi belong to the CO2-outgassing 'N' type according to the classification of Liu and He (1994).
The paper presents an analysis of characteristic karst tufa from Guangxi, China, which has not been studied before. A comparison with tufa from Dinaric Karst of Croatia is discussed in view of the C-type climate. The major mineral is calcite. Minor minerals are quartz and dolomite, depending on location. The content of calcium carbonate varies from 65% to 92%, and that of magnesium carbonate from 0.03% to 1.77%. Among other elements, the most abundant are Fe, from 0.02% to 1.50%, and Ti, from 0.15% to 0.27%. Many other trace elements (V, Cr, Mn, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Y, Zr, Hg and Pb) are also present. Specific activity of radionuclides 40K, 232Th, 137Cs, 226Ra and 238U varies from sample to sample. Concentration of U in tufa is close to that reported for sedimentary carbonate. Low concentration of 137Cs indicates that this part of the world was not exposed to nuclear explosions. The concentration of 226Ra is the highest in Mashan County. The ratio 238U/226Ra (0.21-0.71) in tufa from Mashan County is significantly lower than the theoretical value of 1. In 5 of the 11 studied samples, stable isotopes δ13C and δ18O were analyzed. They were dated by means of the 14C method. One tufa sample originated in the Pleistocene and the others in the Holocene. Because all of the tufa samples contain traces of Na and K, and K < Na, the tufa from Guangxi belong to the CO2-outgassing 'N' type according to the classification of Liu and He (1994).
