摘要
单分子膜在水面上的聚集状态与膜分子的亲水基间的静电排斥作用和疏水基间Van der Waals引力的相对大小有关.在293K亚相温度下,2C_nSNa单分子膜聚集行为的电子显微研究表明,n=12时呈非晶性单分子膜;n=14时在较高的表面压下形成结晶性单分子膜;n=16时可在表面压为0mN·m^(-1)的情况下形成结晶性单分子膜.FT-IR和透射电镜对单分子膜聚集结构的解析结果相互一致.本文还讨论了压缩速度对单分子膜π-A等温线的影响.
The aggregation structure of monolayer was determined by the balance of electrostatic repulsion among anionic hydrophilic groups and Van der Waals attraction among hydrophobic groups. The aggregating behavior of 2C_nSNa monolayer indicated that when n=12, an amorphous monolayer was formed in the whole compressing procedure; when n=14, a crystalline monolayer could be formed at high surface pressure; when n=16, a crystalline monolayer could be formed even at OmN·m^(-1) surface pressure. The results of TEM observation were in accordance with the results of FT-IR analysis. The variation of π-A isotherm with the compression speed was also discussed.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1992年第9期868-873,共6页
Acta Chimica Sinica
