摘要
本文用定向选择的方法,研究了在20K下测定的^(15)N-^(63)Cu-HAP的5:1DMSO-EtOH溶液ENDOR谱,精确测得配体^(15)核的各向异性超超精细耦合张量值和各种不等价~1H核的超超精细耦合张量值.研究结果表明,我们前文的波谱解析,方法是正确的,数据是可靠的.
The ENDOR spectra of the ^(15)N-^(63)Cu-HAP complex measured in 5:1 DMSOEtOH solution at 20 K were studied by orientation selection technique. The anisotrapic superhyperfine coupling tensor of ligand ^(15)N nucleus and the superhyperfine coupling constant of several unequalvalues ~1H nuclei were accurately determined. The result shows that in previous paper the method of spectral analysis is right and the data is reliable.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1992年第7期691-697,共7页
Acta Chimica Sinica
