摘要
双乙烯基甲醇2经过Sharpless不对称环氧化反应合成到高光学纯的午毒蛾Porthetria dispar性信息素(7R,8S)-1a,对映体过量大于99％,总产率达43.9％。
Highly optically pure sex pheromone of gypsy moth porthetria dispar (7R, 8S)-1a was synthesized via asymmetric sharpless epoxidation of a divinylcarbinol 2(>99% e.e.) and the subsequent chemical transformations in an overall yield of 43.9%.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1992年第1期78-84,共7页
Acta Chimica Sinica
