摘要
本文研究了在50%NaOH,CH_2Cl_2体系中,苯骈15-冠-5催化产生的二溴卡宾与苯乙烯、多芳代苯乙烯反应的相对速率常数K_(rel),讨论了苯乙烯α及β位上芳基取代基数目和空间位置对K_(rel)的影响.
Styrene and aryls substituted styrenes were prepared, and the relative rate constants (K_(rel)) of cycloaddition reaction of these substituted styrenes with dibromocarbene were measured under phase transfer catalysis condition.
出处
《华东师范大学学报（自然科学版）》
CAS
CSCD
1992年第2期53-56,共4页
Journal of East China Normal University(Natural Science)
关键词
卡宾
苯乙烯环加成反应
反应动力学
carbene styrene cycloaddition reaction reaction kinetics
