摘要
该文研究了由六次甲基四胺(HA)硝解生成1,3,5-三硝基-1,3,5-三氮杂环己烷(RDX)过程所形成的七种反应产物和中间体的亚甲基在硝酸中的~1H和^(13)C-NMR化学位移。
The ~1 H and ^(13)C NMR chemical shifts of methylene groups innitric acid are reported for 7 products and intermidiates involved in the forma-tion of 1, 3, 5 - trinitro - 1, 3, 5 - triazacyclohexane (RDX ) from the nitroly-sis of hexamethylenetetramine (HA ).
关键词
化学位移
硝胺
亚甲基
NMR
NMR spectra
chemical shifts
nitramine
methylene group