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An improved analysis method of constant-current charge/discharge curves and its application to nickel hydroxide electrode

An improved analysis method of constant-current charge/discharge curves and its application to nickel hydroxide electrode
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摘要 The derivative of charge and discharge curves (d t /d E vs E plot) can be used to describe the charge and discharge process more exactly. The d t /d E ? 獷 plots of nickel hydroxide electrode at different charge/discharge rates and intermittent discharge experiment are discussed. Though the d t /d E ? 獷 plot is affected by many factors, it clearly has intrinsic relation with the nature of active material such as conductivity and thermodynamic potential of active material, which changes with the state of charge. The d t /d E—E plot can also be applied to other electrochemical active materials, especially to those having several phases during charge or discharge. The derivative of charge and discharge curves (d t /d E vs E plot) can be used to describe the charge and discharge process more exactly. The d t /d E ? 獷 plots of nickel hydroxide electrode at different charge/discharge rates and intermittent discharge experiment are discussed. Though the d t /d E ? 獷 plot is affected by many factors, it clearly has intrinsic relation with the nature of active material such as conductivity and thermodynamic potential of active material, which changes with the state of charge. The d t /d E—E plot can also be applied to other electrochemical active materials, especially to those having several phases during charge or discharge.
出处 《中国有色金属学会会刊:英文版》 CSCD 2003年第2期462-466,共5页 Transactions of Nonferrous Metals Society of China
基金 Project( 5 990 2 0 0 4)supportedbytheNationalNaturalScienceFoundationofChina projectsupportedbytheChineseStateKeyLaboratoryforCorrosionandProtection
关键词 镍氢电池 电极 分析方法 改进 放电曲线 nickel hydroxide electrode constant current charge/discharge curve derivative
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参考文献10

  • 1Micka K, Rousar I. Theory of porous electrodes-XVI. The nickel hydroxide electrode[J]. Electrochim Acta, 1980, 25:1085-1090.
  • 2Micka K, Rousar I. Theory of porous electrodes-XVII. Correction for anodic and cathodic reaction rates for nickel hydroxide electrode[J]. Electrochim Acta, 1982, 27: 765-769.
  • 3Weidner J W, Timmerman P. Effect of proton diffusion, electron conductivity, and charge-transfer resistance on nickel hydroxide discharge curves[J]. J Electrochem Soc, 1994, 141: 346-351.
  • 4Heikonen J M, Ploehn H J, White R E. The effect of particle size on the discharge performance of a nickel-metal hydride cell[J]. J Electrochem Soc, 1998, 45: 1840-1847.
  • 5Mao Z, De Vidts P, White R E, et al. Theoretical analysis of the discharge performance of a NiOOH/H2 cell[J]. J Electrochem Soc, 1994, 141: 54-64.
  • 6Guerlou-Demourgues L, Delmas C. Electrochemical behavior of the manganese-substituted nickel hydroxides[J]. J Electrochem Soc, 1996, 143: 561-566.
  • 7Tessier C, Haumesser P H, Bernard P, et al. The structure of Ni(OH)(2): From the ideal material to the electrochemically active one[J]. J Electrochem Soc, 1999, 146: 2059-2067.
  • 8CHEN Hui, WANG Jian-ming, PAN Tao, et al. Effects of coprecipitated zinc on the structure and electrochemical performance of Ni/Al-layered double hydroxide[J]. International Journal of Hydrogen Energy, 2002, 27: 489-496.
  • 9Sugimoto A, Ishida S, Hanawa K. Preparation and characterization of Ni/Al-layered double hydroxide[J]. J Electrochem Soc, 1999, 146: 1251-1255 .
  • 10Dai Jin-xiang, Li Sam F Y, Xiao T D, et al. Structural stability of aluminum stabilized alpha nickel hydroxide as a positive electrode material for alkaline secondary batteries[J]. J Power Sources, 2000, 89: 40-45.

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