摘要
Titanium dioxide nano particles (for example, P25, Germany, Degussa) have been internationally used as an effective photo catalyst for many years. In this paper, characterization of P25, photo degradation ability as well as its life time has been systematically studied by employing methyl orange as a model pollutant. Many factors such as the pH value, pre treatment have been investigated. Just like other nanometer sized or ordinary Anatase TiO2, the catalyst performs better at an optimal pH value. Pre treatment of the catalyst also enhances the photo catalytic ability. And the P25 have shown rather good life time. The degradation products have been characterized by UV, mass and Raman spectrum.It is found that although the P25 photo catalyst has shown excellent decolourization ability, it is still difficult to degrade the methyl orange into small molecule, such as CO2 and H2O. Low power ultraviolet lamps (9W, 254nm) have been used throughout. A comparison experiment has been carried out under natural sunlight, and the results have shown that natural sunlight (With temperature below10℃) could provide even more energy than that of the adopted ultraviolet lamp, which have proved P25 a rather promising photo catalyst for practical application in environment field under natural surrounding. The obtained results may serve as a valuable reference for the evaluation and preparation of high quality TiO2 photo catalyst.
Titanium dioxide nano particles (for example, P25, Germany, Degussa) have been internationally used as an effective photo catalyst for many years. In this paper, characterization of P25, photo degradation ability as well as its life time has been systematically studied by employing methyl orange as a model pollutant. Many factors such as the pH value, pre treatment have been investigated. Just like other nanometer sized or ordinary Anatase TiO2, the catalyst performs better at an optimal pH value. Pre treatment of the catalyst also enhances the photo catalytic ability. And the P25 have shown rather good life time. The degradation products have been characterized by UV, mass and Raman spectrum.It is found that although the P25 photo catalyst has shown excellent decolourization ability, it is still difficult to degrade the methyl orange into small molecule, such as CO2 and H2O. Low power ultraviolet lamps (9W, 254nm) have been used throughout. A comparison experiment has been carried out under natural sunlight, and the results have shown that natural sunlight (With temperature below10℃) could provide even more energy than that of the adopted ultraviolet lamp, which have proved P25 a rather promising photo catalyst for practical application in environment field under natural surrounding. The obtained results may serve as a valuable reference for the evaluation and preparation of high quality TiO2 photo catalyst.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2003年第5期521-526,共6页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.20151001)。
