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The crystal change and "excess heat" produced by long time electrolysis of heavy water with titanium cathode

The crystal change and "excess heat" produced by long time electrolysis of heavy water with titanium cathode
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摘要 According to the theory given in the paper , the long time electrolysis experiment with titanium cathode in heavy water (D 2O) were done for many times by using the open-loop multi-parameters electrolysis calorimetry system, which is established by us. The specialty is that the cathode is titanium rod and the anode is platinum wire. The early experiment result is still repeated in our recent experiment. The obvious "excess heat" phenomenon can take place only when the electrolysis last more than ten days and amount of "excess heat" increased with the electrolysis time. The "excess heat" can also be obtained from the "boiling to dry" experiment. In the recent experiment, we obtain the results that the amount of "excess heat" is about 3.6 times the input energy, the "excess heat" power is 76.5 W, and the "excess heat" power density is 121.7 W/cm 3. After the electrolysis, the crystal structure of the Ti cathode was measured with x-ray diffraction apparatus. We found that the crystal structure of Ti cathode was changed to face-centered cubic structure of TiD 2 from its hexagonal structure. This result is in agreement with the Gou’s theory mentioned in reference . According to the theory given in the paper , the long time electrolysis experiment with titanium cathode in heavy water (D 2O) were done for many times by using the open-loop multi-parameters electrolysis calorimetry system, which is established by us. The specialty is that the cathode is titanium rod and the anode is platinum wire. The early experiment result is still repeated in our recent experiment. The obvious 'excess heat' phenomenon can take place only when the electrolysis last more than ten days and amount of 'excess heat' increased with the electrolysis time. The 'excess heat' can also be obtained from the 'boiling to dry' experiment. In the recent experiment, we obtain the results that the amount of 'excess heat' is about 3.6 times the input energy, the 'excess heat' power is 76.5 W, and the 'excess heat' power density is 121.7 W/cm 3. After the electrolysis, the crystal structure of the Ti cathode was measured with x-ray diffraction apparatus. We found that the crystal structure of Ti cathode was changed to face-centered cubic structure of TiD 2 from its hexagonal structure. This result is in agreement with the Gou's theory mentioned in reference .
出处 《原子与分子物理学报》 CAS CSCD 北大核心 2003年第1期69-74,共6页 Journal of Atomic and Molecular Physics
基金 TheprojectissupportedbyNationalNaturalScienceFoundationofChina(No :10 14 5 0 0 2 )
关键词 重水 电解实验 热力学 物态变化 晶体结构 热量测定 原子核物理 聚变 Electrolysis Heavy water 'Excess heat' Crystal structure Calorimetry
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