摘要
不对称合成是当前有机合成中热门研究领域,利用手性金属络合物催化剂催化不对称硅氢化、烷基化,以烯烃、酮、亚胺、醛等合成手性醇、手性胺、手性酮等具有很好的工业应用前景。本文论述了手性金属络合物催化剂在不对称硅氢化反应及其在二烷基锌对醛的不对称烷基化反应中的应用。
Asymmetric synthesis is one of hot fields in current organic chemistry. Chiral alcohols, amines, and ketone can be prepared by asymmetric hydrosilation and alkylation of olefins, ketones, imines and aldehydes which have perfect industrial prospect. Application of the asymmetric hydrosilation and alkylation using chiral metal coordinate complexes as catalysts are discussed.
出处
《河南化工》
CAS
2003年第2期9-12,共4页
Henan Chemical Industry
