Synthesis of a Tweezer-like Bis(phenylthiapropoxy)calix[4]-arene as a Cation/π Enhanced Sensor for Ion-Selective Electrodes

Synthesis of a Tweezer-like Bis(phenylthiapropoxy)calix[4]-arene as a Cation/π Enhanced Sensor for Ion-Selective Electrodes

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摘要 Two novel 25,27-dihydroxy-26,28-bis(3-phenylthiapropoxy)-calixarene (3) and 25,27-dihydroxy-26,28-bis(3-phenylthia-propoxy)-5,11,17,23-tetra-tert-butylcalixarene (4) were synthesized for the evaluation of their ion-selectivity in ion-selective electrodes (ISEs). ISEs based on 3 and 4 as neutral ionophores were prepared, and their selectivity coefficients for Ag + (lg K pot Ag,M) were investigated against other alkali metal, alkaline-earth metal, aluminum, thallium (I), lead and some transition metal ions using the separate solution method (SSM). These ISEs showed excellent Ag + selectivity over most of the interfering cations examined, except for Hg 2+ and Fe 2+ having relative smaller interference (lg K pot Ag,M≤-2.1). Two novel 25,27-dihydroxy-26,28-bis(3-phenylthiapropoxy)-calixarene (3) and 25,27-dihydroxy-26,28-bis(3-phenylthia-propoxy)-5,11,17,23-tetra-tert-butylcalixarene (4) were synthesized for the evaluation of their ion-selectivity in ion-selective electrodes (ISEs). ISEs based on 3 and 4 as neutral ionophores were prepared, and their selectivity coefficients for Ag + (lg K pot Ag,M) were investigated against other alkali metal, alkaline-earth metal, aluminum, thallium (I), lead and some transition metal ions using the separate solution method (SSM). These ISEs showed excellent Ag + selectivity over most of the interfering cations examined, except for Hg 2+ and Fe 2+ having relative smaller interference (lg K pot Ag,M≤-2.1).

作者孙浩曾宪顺吕监泉冷雪冰陈企发徐风波李庆山何锡文张文勤张正之

出处《Chinese Journal of Chemistry》 SCIE CAS CSCD 2002年第10期1109-1114,共6页 中国化学（英文版）

基金 ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No.2 0 10 2 0 0 3)andthefoundationofNankaiUniversity

关键词 CALIXARENES synthesis silver selectivity ion-selective electrode calixarenes, synthesis, silver selectivity, ion-selective electrode

分类号 O657.1 [理学—分析化学]

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Chinese Journal of Chemistry

2002年第10期

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Synthesis of a Tweezer-like Bis(phenylthiapropoxy)calix[4]-arene as a Cation/π Enhanced Sensor for Ion-Selective Electrodes

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