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新型阳离子聚丙烯酰胺微粒的研究 Ⅲ. 含PEO支链阳离子聚丙烯酰胺微粒的合成、助留性能及作用机理 被引量:8

Novel Cationic Polyacrylamide Microparticles Ⅲ. Synthesis of PEO-Grafted Cationic Polyacrylamide Microparticles, Its Retention Properties and Retention Mechanism
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摘要 采用反相微乳液聚合的方法合成了丙烯酰胺/丙烯酰氧基乙基三甲基氯化铵/聚氧乙烯大单体/N,N′-亚甲基双丙烯酰胺的四元共聚物微粒。研究了该微粒助留剂的结构与性能。这种微粒和纸纤维能够通过离子键和氢键作用,显著地增强助留效果。 The PEO-grafted cationic polyacrylamide microparticles were synthesized via inverse microemulsion tetrapolymerization of acrylamide(AM), acryloyloxyethyl trimethylammonium chloride(ADAMQUAT), PEO-macromonomer(PEO-1000) and N,N′ -methylenebisacrylamide(Bis).The structure and properties of microparticle retention aids were studied.The microparticle could link with pulp fibre through ionic bond and hydrogen bond, from which excellent retention effect of copolymer initiated.
出处 《石油化工》 CAS CSCD 北大核心 2003年第3期216-218,共3页 Petrochemical Technology
基金 广东省自然科学基金资助项目(980506)。
关键词 新型 阳离子聚丙烯酰胺微粒 研究 反相微乳液聚合 四元共聚 微粒助留剂 助留机理 inverse microemulsion polymerization acrylamide tetrapolymerization micro- particle retention aid retention mechanism
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