Synthesis and Structure of Ag_3PSe_4

Synthesis and Structure of Ag_3PSe_4

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摘要 The title compound Ag3PSe4 was synthesized by the reaction of Ag powder, P2Se5 and Se in a molar ratio of 1:1:1 at 500 C and structurally characterized by X-ray crystallography. The crystal belongs to orthorhombic, space group Pmn21 with cell parameters: a = 7.689(4), b = 6.660(3), c = 6.379(4) , V = 326.7(3) 3, Z = 2, Dc = 6.816 g/cm3, Mr = 670.42, F(000) = 584, m = 31.302 mm-1, R = 0.0606, wR = 0.1289 and S = 1.012. The 3-D structure can be regarded as constructed from the stacking of puckered AgPSe honeycomb-like sheets along the c direction, in which the Ag, P and Se atoms are bonded to each other to form a chair-like six-membered ring, and the rings then build the sheets by sharing edges.

作者马宏伟郭国聪陈文通邓镭周国伟董振超黄锦顺

机构地区 State Key Laboratory of Structural Chemistry State Key Laboratory of Structural Chemistry

出处《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2003年第2期161-164,共4页 结构化学（英文）

基金 This work was supported by the National Natural Science Foundation of China (20001007 20131020) Natural Science Foundation of the Chinese Academy of Sciences (KJCX2-H3) and Fujian province (2000F006)

关键词 solid state reaction normal tetrahedral structure metal chalcogenophosphide 硒磷化银合成晶体结构固相反应 X射线分析

分类号 O614.122 [理学—无机化学]

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Chinese Journal of Structural Chemistry

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Synthesis and Structure of Ag_3PSe_4

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