摘要
SrAl2 O4 ∶Eu ,Dy发光材料是近年来发展起来的一种高效的长余辉发光材料 ,具有绿色余辉。本实验对发光材料的粉末进行了粒度分级 ,研究了粒度的大小对发光效果的影响 ,粒度越小发光效果越差。利用扫描电镜分析了发光粉末的化学成分 ,探讨了影响发光的原因。
SrAl 2O 4∶Eu, Dy is a new kind of attractive long-persistent luminescent material with green afterglow. It is necessary to make clear the mechanism of long-persistent luminescence of SrAl 2O 4∶Eu,Dy. This paper was to investigate the effect of powder size on the luminescence of the material. In this work,SrAl 2O 4∶Eu,Dy were made by heating at 1 350℃ for 5 hours in a reducing atmosphere of carbon powders.Then the blocks of SrAl 2O 4∶Eu,Dy were milled into powders and separated by sieves with mesh numbers of 100,200,300,400 and 500,respectively. Also the powders sieved with 500 mesh were further separated by alcohol floatation method. Some white powders with very fine size can be removed from the green powders by alcohol floatation. It was found that the luminescent strength of the powders would decrease when their size become smaller. Among these powders the one separated by 100 mesh sieve has the strongest luminescence. The luminescence of the fine white powders separated by alcohol floatation is very poor,and the rest of the green powders will have better luminescence than that without alcohol floatation. The emission peak position in emission spectrum will not move due to powders size,but the excitation peak position in the excitation spectrum moved towards to short wave length when the powders become smaller. SEM and EDS experiments were carried out to study the size and chemical component of the powders. The white powders have a size of 1～2μm and the green powders have a size of about 20μm after alcohol floatation. In the green powders,Eu component is equal to or more than Dy component. However,in the white powders,Eu component is less than Dy component. It is reasonable to consider that too much Dy caused the luminescence decrease in the white powders.
出处
《发光学报》
EI
CAS
CSCD
北大核心
2003年第1期95-99,共5页
Chinese Journal of Luminescence
