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高分子胆甾相液晶盘状聚集体的结构分析 被引量:3

STRUCTURAL INVESTIGATION OF DISK-LIKE AGGREGATS IN CHOLESTERIC LIQUID CRYSTAL POLYMER
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摘要 利用偏光显微镜,对乙基纤维素/二氯乙酸(EC/DCA)胆甾相液晶的织构进行了研究。当EC/DCA液晶溶液处于两相共存状态时,可以观察到一种典型的胆甾相液晶织构形式——盘状聚集体。结合有效偶极矩模型,推断了分子链在盘状聚集体中的排列方式及盘状聚集体的二维等速生长性质。 In this article, the texture of ethylcellulose/dichloroacetic acid (EC/DCA )cholesteric liguid crystal was in vestigated by means of polarized light microscope, when EC/DCA liquid crystal solution is in biphase state,one typical cholesteric liquid crystal texture,disk-like aggregate,is observed through polarized light microscope. The molecular arrangement in disklike aggregate and its two dimensional equal-rate growth characteristic were deduced by using effective dipole-moment model. .
机构地区 天津大学 南开大学
出处 《高分子材料科学与工程》 EI CAS CSCD 北大核心 1992年第3期71-76,共6页 Polymer Materials Science & Engineering
关键词 高分子 乙基维维素 胆甾相 液晶 ethylcellulose, cholesteric liquid crystal, polarized light microscope, effective dipole-moment model.
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参考文献2

  • 1Huang Yong,J Macromol Sci Phys B,1989年,28卷,1期,131页
  • 2吴法祥,高等学校化学学报,1988年,9卷,12期,1273页

同被引文献9

  • 1赵春田,蔡宝连.乙基纤维素/丙烯酸体系的液晶相行为研究[J].高分子材料科学与工程,1995,11(4):71-76. 被引量:2
  • 2董炎明.乙基纤维素溶致液晶条带织构生长和松弛的动态过程[J].厦门大学学报(自然科学版),1995,34(6):928-934. 被引量:1
  • 3Natarajan L V, Bunning T J,Kim S Y. Photochromic liquid crystalline cyclic siloxanes containing spiropyran groups[J]. Macromolecules, 1994,27:7248-7253.
  • 4Hattori H, Uryu T. Synthesis and properties of photochromic liquid crystalline copolymer containing both spironaphthoxazine and cholesteryl groups[J]. J Polymer Science Part A, Polymer Chemistry, 2000,38:887-894.
  • 5Barmatov E B, Bobrovsky A Y, Pebalk D A,et al. Cholesteric mesophase of the hydrogen-bonded blends of liquid crystalline ionogenic copolymer with a low molecular weight chiral dopont[J]. J Poly Sci Part A,Poly Chem, 1999,37:3215-3225.
  • 6Mihara T, Nomura K, Funaki K. Induced cholesteric liuid crystalline polymers[J]. Polymer Journal, 1997,29(4):309-315.
  • 7Xue M G, Chen Y Y,He Y E. Synthesis and propertied of cholesteric liquid crystal crown ether[J]. Mol Cryst Liq Cryst, 1991,209:213-223.
  • 8Espinosa M A, Cadiz V, Calia M. New cholesterol liquid-crystal epoxy resins derived from 6-hydroxy-20naphthoic[J]. J Poly Sci Part A, Poly Chem, 2001,39:2847-2858.
  • 9Rukmani S, Ganga R. Synthesis and characterization of liquid-crystalline polyesters with chiral and achrial twin spacers[J]. J Poly Sci Part A, Poly Chem, 2001,39:1743-1752.

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